Self-Healing Supramolecular Flexible Network of Zn(II): Exploring Chemo-Responsiveness, Antimicrobial Efficiency, and Variable Microelectronic Device Performances DOI

Deblina Saha,

Tamal Dey,

Indrajit Pal

et al.

Langmuir, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 30, 2024

The Zn(II)-supramolecular metallogel (i.e., Zn-Py) of 2,6-pyridinedicarboxylic acid was prepared through the addition a metal source and as low molecular weight gelator. Zn-Py encapsulated N,N′-dimethylformamide gel-immobilized polar aprotic solvent media. mechanical features synthesized were investigated. thixotropic behavior also analyzed. microscopic feature imaged FESEM TEM studies. EDS pattern ratified role different gel-building chemical constituents. stimuli responsiveness tested. metallogel-forming mechanistic protocol visualized FTIR ESI mass spectroscopic analyses. bioeffectiveness, i.e., antimicrobial potency, studied. efficiency against both Gram +ve −ve bacteria including Salmonella typhimurium (MTCC 98), Escherichia coli 1667), Bacillus cereus (ATCC 13061), Listeria monocytogenes 657), Staphylococcus aureus 96) critically images live damaged due to action experimentally used fabricate heterojunction Schottky-type photodetectors show their excellent light–matter interaction potentiality active material in optoelectronics. electrical parameters semiconductor diodes such p–n junction Schottky diode fabricated by Outcomes experimental investigation demonstrated that tested effectively showed parameters, especially with ideality factor (η) 1.3 under dark environment. This device efficiently depicted great ON/OFF ratio 33.4 at reverse bias voltage −2 V. metal–semiconductor–metal (M-S-M) junction-type barrier using where Au/Zn-Py metallogel/Au-based fabrication strategy implemented.

Language: Английский

In Situ Synthesis of Luminescent CdSe Quantum Dots Embedded in Cd(II) Metallohydrogels: A Hybrid Material for Selective and Naked-Eye Sensing of Hg22+ Ions DOI
Sougata Sarkar, Pradip K. Maji, Tarak Nath Das

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 9, 2025

In situ synthesis and stabilization of quantum dots (QDs) with unique features toward environmental remediation is an area current interest. Our present study has addressed the spontaneous formation a metallohydrogel Cd(II) mixed ligand system (sodium azide 4,5-dicyanoimidazole). The gelation was highly selective to all three components only achieved when were together. Impact different pure solvent systems on metallogelation also studied. Spontaneous high-yield growth fibrous bundled nanostructures, majorly resulting from metal-ligand coordination in association solvent-anticipated hydrogen-bonding interactions, are observed. overall gel integrity corresponding nanostructure exhibit stimulus-responsive behavior various external stimuli. pristine metallogel then explored as scaffold for fabrication CdSe QD) which remain fastened fibers. QD-tethered luminescent nature where emission could be easily tuned. Finally, this hybrid [i.e., CdSe-tethered metallohydrogel] successfully employed material naked-eye sensing toxic heavy metal ion Hg22+ down micromolar level. This thus highlights potential such metallo-supramolecular hydrogel photophysics remediation.

Language: Английский

Citations

0
Dynamic Covalent and Noncovalent Bonds Based Self‐assembled Biomaterials: From Construction to Biomedical Applications DOI
Chengfei Liu, Y. Jin, Jia‐Qi Li

et al.

Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 20, 2025

Comprehensive Summary Self‐assembly processes are ubiquitous in biological systems, playing essential roles sustaining life activities. The exploration of self‐assembled biomaterials (SABMs) holds great potential for advancing various fields, particularly biomedicine and materials science. Because the unique reversibility responsiveness to stimuli, dynamic covalent bonds (DCBs) noncovalent (NCBs) endow SABMs with self‐healing properties, stimuli controllable degradation, making them highly versatile a wide range biomedical applications. In this article, recent advances future trends based on DCBs NCBs thoroughly reviewed. We begin by introducing molecular principles characteristics that govern formation SABMs. also explore responsive functional features these detail. Finally, we summarize perspectives challenges associated development aim review offer comprehensive overview SABMs, serving as valuable resource chemists scientists striving further advance design Key Scientists

Language: Английский

Citations

0
Remarkable Stability of Glutathione-Based Supramolecular Gel in the Presence of Oxidative Stress from Hydrogen Peroxide DOI

Md Azimuddin Sk,

Reena Kyarikwal,

Kalyan K. Sadhu

et al.

ACS Applied Bio Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 30, 2024

Low molecular weight 7-methoxy-3-(

Language: Английский

Citations

3
Self-Healing Supramolecular Flexible Network of Zn(II): Exploring Chemo-Responsiveness, Antimicrobial Efficiency, and Variable Microelectronic Device Performances DOI

Deblina Saha,

Tamal Dey,

Indrajit Pal

et al.

Langmuir, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 30, 2024

The Zn(II)-supramolecular metallogel (i.e., Zn-Py) of 2,6-pyridinedicarboxylic acid was prepared through the addition a metal source and as low molecular weight gelator. Zn-Py encapsulated N,N′-dimethylformamide gel-immobilized polar aprotic solvent media. mechanical features synthesized were investigated. thixotropic behavior also analyzed. microscopic feature imaged FESEM TEM studies. EDS pattern ratified role different gel-building chemical constituents. stimuli responsiveness tested. metallogel-forming mechanistic protocol visualized FTIR ESI mass spectroscopic analyses. bioeffectiveness, i.e., antimicrobial potency, studied. efficiency against both Gram +ve −ve bacteria including Salmonella typhimurium (MTCC 98), Escherichia coli 1667), Bacillus cereus (ATCC 13061), Listeria monocytogenes 657), Staphylococcus aureus 96) critically images live damaged due to action experimentally used fabricate heterojunction Schottky-type photodetectors show their excellent light–matter interaction potentiality active material in optoelectronics. electrical parameters semiconductor diodes such p–n junction Schottky diode fabricated by Outcomes experimental investigation demonstrated that tested effectively showed parameters, especially with ideality factor (η) 1.3 under dark environment. This device efficiently depicted great ON/OFF ratio 33.4 at reverse bias voltage −2 V. metal–semiconductor–metal (M-S-M) junction-type barrier using where Au/Zn-Py metallogel/Au-based fabrication strategy implemented.

Language: Английский

Citations

2