Au-Acyclic Diaminocarbene-Linked Porphyrin Covalent Organic Framework as a Cascade Catalyst for Photocatalytic Sulfide Oxidation and Intermolecular Nucleophilic Addition

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

The design and synthesis of a multifunctional covalent organic framework (COF) for various applications have been considered big challenge. Herein, we report the construction novel porphyrin-based Au-acyclic diaminocarbene (Au-ADC)-linked COF (abbreviated as Au-ADC-Por-COF) via metal-mediated nucleophilic addition reaction. resultant Au-ADC-Por-COF revealed an outstanding performance in cascade catalyzing photocatalytic sulfide oxidation under visible-light irradiation intermolecular addition. This research might open new way advanced materials with unprecedented structures catalytic activities.

Language: Английский

Dimensionality control of chiral covalent organic frameworks for enhanced asymmetric catalysis

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163613 - 163613

Published: May 1, 2025

Language: Английский