Role of Interface of Metal–Organic Frameworks and Their Composites in Persulfate-Based Advanced Oxidation Process for Water Purification DOI

Jianke Tan,

Xiaodan Zhang,

Yuwan Lu

et al.

Langmuir, Journal Year: 2023, Volume and Issue: 40(1), P. 21 - 38

Published: Dec. 25, 2023

The persulfate activation-based advanced oxidation process (PS-AOP) is an important technology in wastewater purification. Using metal-organic frameworks (MOFs) as heterogeneous catalysts the PS-AOP showed good application potential. Considering intrinsic advantages and disadvantages of MOF materials, combining MOFs with other functional materials has also shown excellent PS activation performance even achieves certain expansion. This Review introduces classification MOF-based composites latest progress their systems. relevant activation/degradation mechanisms are summarized discussed. Moreover, importance catalyst-related interfacial interaction for developing optimizing systems emphasized. Then, interference behavior environmental parameters on reaction analyzed. Specifically, initial solution pH coexisting inorganic anions may hinder via consumption reactive oxygen species, affecting process. aims to explore summarize mechanism PS. Hopefully, it will inspire researchers develop new AOP strategies more prospects.

Language: Английский

Structural dependency of pyridine carboxylic acid isomers in metal-organic coordination adsorption for copper corrosion inhibition DOI
Jihoon Seo, Seokgyu Ryu, Jiseok Kwon

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: 663, P. 160149 - 160149

Published: April 23, 2024

Language: Английский

Citations

4
Pristine metal-organic framework electrocatalysts for hydrogen production: Role of electrocatalyst properties in basic media DOI Creative Commons
Liberty L. Mguni, Olga K. Mmelesi, Emmanuel Kweinor Tetteh

et al.

Cleaner Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 100170 - 100170

Published: April 1, 2025

Language: Английский

Citations

0
The Role of Metal–Organic Framework Induced Confinement Effects on Molecular Electrocatalysts Relevant to the Energy Transition DOI Creative Commons
Marlene E. Hoefnagel, Dennis G. H. Hetterscheid

ChemSusChem, Journal Year: 2025, Volume and Issue: unknown

Published: April 24, 2025

Metal organic frameworks (MOFs) are promising materials for (electro)catalysis as they can improve stability, reusability, and catalytic current densities of molecular catalysts, thereby combining the advantages homogeneous‐ heterogeneous catalysts. However, much is unknown about effects confinement a catalyst within an MOF on overall behavior. The performance series electrocatalysts confined in MOFs compared to that corresponding homogeneous catalysts evaluate what extend site affected by terms activity, selectivity. Together examples discuss depict happens when it incorporated into MOF, recommendations made how electrochemical activity way allows description such performance. It noted limiting factor reaction found 1) slow electron transport, 2) mass transport reactants products, or 3) low itself. Understanding changes mass‐ resulting mechanism essential be able bring systems practical applications.

Language: Английский

Citations

0
Engineering a molecular ruthenium catalyst into three-dimensional metal covalent organic frameworks for efficient water oxidation DOI Creative Commons

Wang‐Kang Han,

Yong Liu,

Jingdong Feng

et al.

Chemical Science, Journal Year: 2023, Volume and Issue: 14(42), P. 11768 - 11774

Published: Jan. 1, 2023

Three-dimensional metal covalent organic frameworks (3D MCOFs) were constructed by integrating molecular ruthenium water oxidation catalysts (WOCs) for realizing efficient oxidation.

Language: Английский

Citations

10
Role of Interface of Metal–Organic Frameworks and Their Composites in Persulfate-Based Advanced Oxidation Process for Water Purification DOI

Jianke Tan,

Xiaodan Zhang,

Yuwan Lu

et al.

Langmuir, Journal Year: 2023, Volume and Issue: 40(1), P. 21 - 38

Published: Dec. 25, 2023

The persulfate activation-based advanced oxidation process (PS-AOP) is an important technology in wastewater purification. Using metal-organic frameworks (MOFs) as heterogeneous catalysts the PS-AOP showed good application potential. Considering intrinsic advantages and disadvantages of MOF materials, combining MOFs with other functional materials has also shown excellent PS activation performance even achieves certain expansion. This Review introduces classification MOF-based composites latest progress their systems. relevant activation/degradation mechanisms are summarized discussed. Moreover, importance catalyst-related interfacial interaction for developing optimizing systems emphasized. Then, interference behavior environmental parameters on reaction analyzed. Specifically, initial solution pH coexisting inorganic anions may hinder via consumption reactive oxygen species, affecting process. aims to explore summarize mechanism PS. Hopefully, it will inspire researchers develop new AOP strategies more prospects.

Language: Английский

Citations

10