Amorphous PdSe/crystalline Pt heterostructure enhances polyhydric alcohols electrooxidation DOI
Jie Li, Mengyun Hu, Tianpeng Liu

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110828 - 110828

Published: Jan. 1, 2025

Language: Английский

Facet-Controlled Synthesis of Unconventional-Phase Metal Alloys for Highly Efficient Hydrogen Oxidation DOI
Xixi Wang, Yiyao Ge, Mingzi Sun

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(34), P. 24141 - 24149

Published: Aug. 20, 2024

Facet control and phase engineering of metal nanomaterials are both important strategies to regulate their physicochemical properties improve applications. However, it is still a challenge tune the exposed facets with unconventional crystal phases, hindering exploration facet effects on functions. In this work, by using Pd nanoparticles hexagonal close-packed (hcp, 2H type) phase, referred as 2H-Pd, seeds, selective epitaxial growth method developed predominant directions secondary materials forming Pd@NiRh nanoplates (NPLs) nanorods (NRs) 2H-Pd@2H-NiRh NPLs NRs, respectively. The NRs expose more (100)h (101)h 2H-NiRh shells compared NPLs. Impressively, when used electrocatalysts toward hydrogen oxidation reaction (HOR), show superior activity NiRh alloy conventional face-centered cubic (fcc) (fcc-NiRh) NPLs, revealing crucial role in enhancing catalytic performance unconventional-phase nanomaterials. Density functional theory (DFT) calculations further unravel that excellent HOR can be attributed shells, which possess high electron transfer efficiency, optimized H* binding energy, enhanced OH* low energy barrier for rate-determining step during process.

Language: Английский

Citations

5
MOF-derived phase-selective synthesis of ln2O3 with appropriate surface atomic arrangement for CO2 photoreduction DOI
Yunzhe Wang,

Wanyue Qian,

Ganghua Zhou

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 501, P. 157513 - 157513

Published: Nov. 8, 2024

Language: Английский

Citations

5
The cation exchange driving multi-phase regulation in Co7Fe3/Co@NC for enhanced broadband electromagnetic wave absorption DOI

Xingyue Zhou,

Xiaohan Wu,

Siyue Li

et al.

Carbon, Journal Year: 2024, Volume and Issue: 230, P. 119592 - 119592

Published: Aug. 31, 2024

Language: Английский

Citations

4
General Synthesis of Wurtzite Cu-Based Quaternary Selenide Nanocrystals via the Colloidal Method DOI
Song Chen,

Bingfeng Zu,

Qiren Jin

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Cu-based multinary selenide nanomaterials have garnered significant attention in photocatalytic and photovoltaic applications, owing to their unique electronic optical properties. However, the high-yield scalable synthesis of wurtzite colloidal nanocrystals via a versatile simple method has not yet been achieved. In this work, we report general hot-injection for diverse library quaternary nanocrystals, including Cu2CdSnSe4, Cu2ZnSnSe4, Cu2FeSnSe4, Cu2CoSnSe4, Cu2MnSnSe4, Cu3InSnSe5, Cu3GaSnSe5, CuZnInSe3, CuZnGaSe3, CuCdInSe3, Cu(InGa)Se2. As proof concept, Cu2CdSnSe4 are used as photocatalysts solar-to-hydrogen production, displaying good hydrogen evolution performance. Moreover, approach broad applicability other nanomaterials, which show potential wide range applications.

Language: Английский

Citations

0
Amorphous PdSe/crystalline Pt heterostructure enhances polyhydric alcohols electrooxidation DOI
Jie Li, Mengyun Hu, Tianpeng Liu

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110828 - 110828

Published: Jan. 1, 2025

Language: Английский

Citations

0