The Journal of Physical Chemistry C, Journal Year: 2025, Volume and Issue: unknown
Published: March 2, 2025
Language: Английский
Nature Chemistry, Journal Year: 2024, Volume and Issue: 17(1), P. 29 - 37
Published: Oct. 25, 2024
Language: Английский
Citations
7
The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: 15(24), P. 6370 - 6374
Published: June 10, 2024
The inverse spin-galvanic effect or current-induced spin-polarization is mainly associated with interfaces between different layers in semiconducting heterostructures, surfaces of metals, and bulk materials. Here, we theoretically predict that the should also be present chiral molecules, as a result induced spin selectivity effect. As proof-of-principle, calculate nonequilibrium properties model system previously has been successfully used to explain multitude aspects related Here show current driven molecule gives rise magnetic moment sensitive external magnet field. then behaves like soft ferromagnet. This, turn, suggests permeability measurement otherwise nonmagnetic systems may noninvasively detect presence spin-polarized currents.
Language: Английский
Citations
5
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)
Published: July 4, 2024
To facilitate the transition from a carbon-energy-dependent society to sustainable society, conventional engineering strategies, which encounter limitations associated with intrinsic material properties, should undergo paradigm shift. From theoretical viewpoint, spin-dependent feature of oxygen evolution reaction (OER) reveals potential spin-polarization strategy in enhancing performance electrochemical (EC) reactions. The chirality-induced spin selectivity (CISS) phenomenon attracts unprecedented attention owing its utility achieving novel breakthroughs. This paper starts experimental results aimed at efficiency OER focusing on EC system based CISS phenomenon. applicability is verified through various analytical methodologies clarify groundwork and mechanisms underlying pathway. discussion then extended effective spin-control strategies photoelectrochemical effect. Exploring influence spin-state control kinetic thermodynamic aspects, this perspective also discusses effect polarization induced by OER. Lastly, future directions for redox systems are discussed, including expansion chemical reactions development materials capabilities.
Language: Английский
Citations
5
The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: 15(25), P. 6605 - 6610
Published: June 17, 2024
The cooperativity in artificial self-assembling systems can be enhanced to expand their applications and redesign properties. Recently, chiral molecules have garnered renewed attention due potential as highly efficient spin filters through the chiral-induced selectivity (CISS) effect. However, of asymmetric building blocks based on perylene diimides (PDIs) self-assembled materials generate a spin-polarized current is still not widely acknowledged. In this work, we demonstrated that nanofibers derived from "asymmetric PDIs" been found exhibit promising spin-filtering property amplification polarization at room temperature. Also, exploration correlating it with reported for first time work. These findings underscore significance realm spintronics, they offer fascinating platforms evolving structure–property relationship. It also provides feasible possibility enhancing CISS-based spintronic devices accomplish controllability high efficiency simultaneously.
Language: Английский
Citations
4
npj 2D Materials and Applications, Journal Year: 2025, Volume and Issue: 9(1)
Published: Jan. 7, 2025
Abstract We present the first investigation of unusual nonlinear Hall effects in twisted multilayer 2D materials. Contrary to expectations, our study shows that these are not merely extensions their monolayer counterparts. Instead, we find stacking order and pairwise interactions between neighboring layers, mediated by Berry curvatures, play a pivotal role shaping collective optical response. By combining large-scale Real-Time Time-Dependent Density Functional Theory (RT-TDDFT) simulations with model Hamiltonian analyses, demonstrate remarkable second-harmonic transverse response hexagonal boron nitride four-layers, even cases where total curvature cancels out. Furthermore, symmetry analysis layered structures provides simplified framework for predicting responses materials general. Our challenges prevailing understanding opens new avenues design development advanced tailored properties.
Language: Английский
Citations
0
Precision Chemistry, Journal Year: 2025, Volume and Issue: 3(2), P. 51 - 71
Published: Jan. 10, 2025
The past few decades have witnessed significant development in intercalation chemistry research aimed at precisely controlling material properties. Intercalation, as a powerful surface and interface synthesis strategy, facilitates the insertion of external guests into van der Waals (vdW) gaps two-dimensional (2D) layered materials, inducing various modulation effects (the weakening interlayer interactions, changes electronic structures, interfacial charge transfer, symmetry manipulation) to tailor properties while preserving intralayer covalent bonds. Importantly, benefiting from very diverse structures organic molecules, their enables integration molecules with wide array 2D resulting creation numerous organic–inorganic hybrid superlattices exotic properties, which brings extensive potential applications fields such spintronics, superconductor electronics, optoelectronics, thermoelectrics. Herein, based on recent advancements systems, we briefly discuss summary classification guest species. We also three induced by further introduce intriguing modulations physicochemical including superconductivity, magnetism, thermoelectricity thermal conductivity, chiral-induced spin selectivity (CISS) effects, interlayer-confined chemical reaction. Finally, offer insights future opportunities emerging challenges systems.
Language: Английский
Citations
0
Theoretical and Experimental Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 14, 2025
Language: Английский
Citations
0
Chemical Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The chiral molecular structure and local inversion asymmetry of inorganic octahedrons, beyond global chirality, significantly influence the spin-related properties perovskites.
Language: Английский
Citations
0
Accounts of Chemical Research, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 28, 2025
ConspectusSymmetry is a pervasive phenomenon spanning diverse fields, from art and architecture to mathematics science. In the scientific realms, symmetry reveals fundamental laws, while breaking─the collapse of certain symmetry─is underlying cause phenomena. Research on breaking consistently provides valuable insights across disciplines, parity violation in physics origin homochirality biology. Chemistry particularly rich studies, encompassing areas such as asymmetric synthesis, chiral resolution, structure assembly, so on. Across different well-defined methodology necessary analyze or nature behind phenomenon, enabling researchers uncover principles mechanisms. Basically, three key points underpin symmetry-related research: scale-dependency symmetry/symmetry breaking, driving force phenomena, properties arising breaking.This Account will focus aforementioned elucidated with organic cages proof-of-concept models, exhibit shape-persistent 3D molecular frameworks, motion, high propensity for crystallization.First, we examine racemization processes dynamic motions illustrate that are time-scale-dependent. Specifically, racemization, driven by influenced hydrogen bonding rigidity cage framework, which may not be observable within experimental temporal scale. This determines whether enantiomeric excess system, namely, broken can detected experimentally. We also investigate hierarchical structures self-assembled racemic cages, demonstrating asymmetry manifest differently spatial scales, supramolecular macroscopic levels. Second, discuss spontaneous resolution─a classic symmetry-breaking event during crystallization─from thermodynamic perspective. suggest compounds, compared conglomerates, more entropy-favored, explaining their greater prevalence nature. Spontaneous resolution take place only when favorable enthalpy compensates unfavorable entropy. conglomerates composed strong intermolecular interactions along screw axes provide compensation. Finally, explore unique emerge symmetry-broken packing crystals racemates, second-harmonic generation piezoelectricity. It turns out operation plays critical role determining material properties. By comprehensively analyzing this into phenomena disciplines. paves way designing novel materials tailored applications optics, electronics, beyond.
Language: Английский
Citations
0
The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1629 - 1633
Published: Feb. 5, 2025
Redox processes that involve pairs of electrons are common in nature. Some these reactions oxygen molecules. The understanding the efficiency reduction reaction (ORR), for example, is a challenge since spin forbidden and requires transfer two electrons. Past experimental theoretical studies demonstrated by controlling transferred electrons, it possible to overcome barrier resulting from mismatch between reactants products. In other works, was suggested enhanced if each pair have phase relation, namely, they possess property triplet state. Since nature through chiral systems, we probed chirality affects formation paired with same spin, like model calculations demonstrate enhances probability electron pairing states, even at room temperature. This enhancement originates breaking degeneracy, enabled interaction spins vibrations.
Language: Английский
Citations
0