Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 111093 - 111093
Published: April 1, 2025
Language: Английский
Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 111093 - 111093
Published: April 1, 2025
Language: Английский
Solar Energy, Journal Year: 2024, Volume and Issue: 279, P. 112806 - 112806
Published: Aug. 2, 2024
Language: Английский
Citations
6Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(48)
Published: Aug. 5, 2024
Abstract Mixed tin‐lead perovskite solar cells can reach band gaps as low 1.2 eV, offering high theoretical efficiency and serving base materials for all‐perovskite tandem cells. However, instability defect densities at the interfaces, particularly buried surface, have limited performance improvements. In this work, we present modification of bottom interface with multifunctional hydroxylamine salts. These salts effectively coordinate different components, having critical influences in regulating crystallization process passivating defects varying nature. The surface reduced traps prevented formation excessive lead iodide, enhancing quality films. modified devices presented fill factors reaching 81 % efficiencies up to 23.8 %. unencapsulated maintained over 95 their initial after 2000 h shelf storage.
Language: Английский
Citations
4Materials Today Energy, Journal Year: 2024, Volume and Issue: 45, P. 101692 - 101692
Published: Sept. 6, 2024
Language: Английский
Citations
4ACS Applied Electronic Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 17, 2025
Tin–lead (Sn–Pb) mixed perovskites have emerged as promising light-absorbing materials for single-junction and all-perovskite tandem solar cells due to their favorable narrow bandgaps high theoretical power conversion efficiencies. However, the easy oxidation of Sn2+ Sn4+ results in formation rampant defects during fast crystallization Sn–Pb perovskite thin films remarkable photovoltaic performance decay under operation, impeding practical applications. Herein, this spotlight presents intrinsic origins instability summarizes recent advances antioxidation strategies regarding raw material purification, additive engineering, composition interfacial engineering. Then, remaining challenges future directions are discussed inspire more rational design toward efficient durable cells.
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 22, 2025
High defect concentrations at the interfaces are basis of charge extraction losses and instability in perovskite solar cells. Surface engineering with organic cations is a common practice to solve this issue. However, full implications counteranions these for device functioning often neglected. In work, we used 4-fluorophenethylammonium cation varying halide modification both methylammonium-free Pb-based n-i-p devices, observing significant differences among iodide, bromide, chloride. The treatment buried top resulted improved surface quality films largely carrier dynamics reduced nonradiative recombination. Consequently, optimal interface-modified cells surpassed 20% efficiency demonstrated remarkable operational stability. Our findings underscore potential comprehensive strategies advancing film quality, thereby facilitating their broader more successful applications.
Language: Английский
Citations
0Materials Today Electronics, Journal Year: 2025, Volume and Issue: unknown, P. 100138 - 100138
Published: Jan. 1, 2025
Language: Английский
Citations
0Optical Materials, Journal Year: 2025, Volume and Issue: unknown, P. 116701 - 116701
Published: Jan. 1, 2025
Language: Английский
Citations
0Communications Physics, Journal Year: 2025, Volume and Issue: 8(1)
Published: Feb. 16, 2025
Language: Английский
Citations
0physica status solidi (a), Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 19, 2025
The first‐ever investigation on rudorffite/silicon‐based two‐terminal (2T) tandem solar cells is presented in this innovative study, which investigates their potential to achieve unprecedented levels of efficiency. Thus, the only way improve conversion efficiency rudorffite photovoltaic systems would be use multijunction or ideas. For three distinct materials—Ag 3 BiI 6 (1.71 eV), Ag 2 5 (1.90 and AgBiI 4 (1.87 eV)—a number parameters, including absorber thickness, electron transport layer hole defects, interference are optimized. every material, optimization efforts produce outstanding results that led a notable increase increases from 5.77% remarkable 15.26%. Similarly, there significant improvement , with an 4.10 10.59%. Finally, shows improvement, increasing 4.06 10.44%. 2T double‐junction cell configuration investigated by combining top silicon‐based bottom cells. According results, 22.31, 18.63, 18.89%, respectively, showing improvements over single‐cell counterparts.
Language: Английский
Citations
0Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
Abstract Metal halide perovskite‐based devices can exhibit exceptional optoelectronic performance at relatively high defect densities, a phenomenon commonly referred to as tolerance, which is one of the most important features metal perovskites (MHPs). Defect tolerance previously thought be static property, determined solely by composition and manufacturing process. However, recent studies have shown that MHPs dynamic vary over time. For example, power conversion efficiency MHPs‐based solar cells has been found improve significantly under continuous illumination. Although this unique self‐optimization behavior MHPs, it seriously affect stability output in real‐world operating conditions. In view this, extensive research conducted, but physical mechanism photoinduced (DDT) remained inconclusive, both mechanisms experimental phenomena continue subjects controversy. Therefore, timely summarization on related DDT urgently needed. review, systematic overview first provided phenomena, characteristics, influencing factors DDT. Following that, proposed for are summarized, with focus carrier‐defect carrier‐lattice interactions. Finally, current challenges faced summarized an outlook future developments provided. This review aims offer comprehensive understanding enhance cells, thereby facilitating advancement commercialization these technologies.
Language: Английский
Citations
0