Chemical Science,
Journal Year:
2021,
Volume and Issue:
12(20), P. 6772 - 6799
Published: Jan. 1, 2021
MOFs
are
promising
candidates
for
the
capture
of
toxic
gases
such
as
SO2,
H2S,
NH3
and
NOx.
Understanding
role
different
chemical
functionalities,
within
pores
MOFs,
is
key
accomplishing
superior
captures
these
gases.
Chemical Reviews,
Journal Year:
2021,
Volume and Issue:
121(7), P. 3751 - 3891
Published: Feb. 25, 2021
Among
the
recent
developments
in
metal-organic
frameworks
(MOFs),
porous
layered
coordination
polymers
(CPs)
have
garnered
attention
due
to
their
modular
nature
and
tunable
structures.
These
factors
enable
a
number
of
properties
applications,
including
gas
guest
sorption,
storage
separation
gases
small
molecules,
catalysis,
luminescence,
sensing,
magnetism,
energy
conversion.
MOFs,
two-dimensional
(2D)
compounds
are
also
known
as
2D
CPs
or
MOFs.
Since
discovery
graphene
2004,
materials
been
widely
studied.
Several
MOFs
suitable
for
exfoliation
ultrathin
nanosheets
similar
other
materials,
making
these
structures
useful
unique
various
technological
applications.
Furthermore,
fascinating
topological
networks
entanglements.
This
review
provides
an
overview
different
aspects
MOF
architectures
such
topology,
interpenetration,
structural
transformations,
properties,
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(9), P. 9078 - 9144
Published: March 28, 2022
In
the
past
two
decades,
metal-organic
frameworks
(MOFs)
or
porous
coordination
polymers
(PCPs)
assembled
from
metal
ions
clusters
and
organic
linkers
via
metal-ligand
bonds
have
captivated
significant
scientific
interest
on
account
of
their
high
crystallinity,
exceptional
porosity,
tunable
pore
size,
modularity,
diverse
functionality.
The
opportunity
to
achieve
functional
materials
by
design
with
promising
properties,
unattainable
for
solid-state
in
general,
distinguishes
MOFs
other
classes
materials,
particular,
traditional
such
as
activated
carbon,
silica,
zeolites,
thereby
leading
complementary
properties.
Scientists
conducted
intense
research
production
chiral
MOF
(CMOF)
specific
applications
including
but
not
limited
recognition,
separation,
catalysis
since
discovery
first
CMOF
(i.e.,
d-
l-POST-1).
At
present,
CMOFs
become
interdisciplinary
between
chirality
chemistry,
material
which
involve
many
subjects
physics,
optics,
medicine,
pharmacology,
biology,
crystal
engineering,
environmental
science,
etc.
this
review,
we
will
systematically
summarize
recent
progress
regarding
strategies,
synthetic
approaches,
cutting-edge
applications.
highlight
successful
implementation
asymmetric
catalysis,
enantioselective
sensing.
We
envision
that
review
provide
readers
a
good
understanding
chemistry
and,
more
importantly,
facilitate
endeavors
rational
multifunctional
industrial
implementation.
Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
123(11), P. 6953 - 7024
Published: March 22, 2023
Functional
phase
change
materials
(PCMs)
capable
of
reversibly
storing
and
releasing
tremendous
thermal
energy
during
the
isothermal
process
have
recently
received
attention
in
interdisciplinary
applications.
The
smart
integration
PCMs
with
functional
supporting
enables
multiple
cutting-edge
applications,
including
optical,
electrical,
magnetic,
acoustic,
medical,
mechanical,
catalytic
disciplines
etc.
Herein,
we
systematically
discuss
storage
mechanism,
transfer
conversion
summarize
state-of-the-art
advances
applications
PCMs.
In
particular,
are
still
their
infancy.
Simultaneously,
in-depth
insights
into
correlations
between
microscopic
structures
thermophysical
properties
composite
revealed.
Finally,
current
challenges
future
prospects
also
highlighted
according
to
up-to-date
This
review
aims
arouse
broad
research
interest
community
provide
constructive
references
for
exploring
next
generation
advanced
multifunctional
thereby
facilitating
major
breakthroughs
both
fundamental
researches
commercial
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(3), P. 1045 - 1097
Published: Jan. 1, 2022
This
review
illustrates
molecular-scale
confinement,
containment,
isolation,
and
related
concepts
to
present
MOF-centric
catalysts
realize
desired
chemical
transformations.
Accounts of Chemical Research,
Journal Year:
2022,
Volume and Issue:
55(4), P. 579 - 591
Published: Feb. 3, 2022
ConspectusCurrent
global
crises
related
to
clean
energy
and
the
environment
entail
development
of
materials
that
are
capable
addressing
these
challenges.
Metal–organic
frameworks
(MOFs),
a
class
functional
assembled
from
metal-containing
nodes
organic
ligands
via
coordination
bonds,
have
been
successfully
developed
for
various
applications,
including
catalysis,
toxic
chemical
removal,
gas
storage
separation,
as
result
their
highly
tailorable
nature
precisely
engineered
pore
structures.
In
particular,
exceptionally
high
surface
areas
porosities
MOFs
two
most
attractive
characteristics
place
them
among
best
porous
gases,
such
hydrogen
methane.
Reticular
chemistry
stands
out
prominent
approach
design
this
strategy
allows
rational
top-down
guided
by
topological
nets
afford
extended
framework
structures
with
precise
architectural
arrangements
at
molecular
level.
Bridging
gap
between
reticular
strategies
can
facilitate
next-generation
high-performance
through
state-of-the-art
design.In
Account,
we
summarize
our
group's
efforts
over
past
few
years
toward
synthesis
applications
inspired
chemistry.
First,
describe
how
leveraged
synthesize
NU-1500,
which
is
based
on
6-connected
edge-transitive
acs
net,
assembly
triptycene-based
high-valent
metal
trimers.
This
delicate
amenable
isoreticular
expansion,
an
additional
phenyl
group
in
rigid
ligand
NU-1500
yields
NU-1501.
Importantly,
NU-1501-Al
exhibits
both
gravimetric
Brunauer–Emmett–Teller
(BET)
area
7310
m2
g–1,
current
record
after
satisfying
four
BET
consistency
criteria,
volumetric
2060
cm–3.
The
porosity
NU-1501
promising
adsorbents
methane
hydrogen.
Second,
illustrate
stable
Zr-MOFs
nets:
(1)
successful
expansions
NU-1000
(a
4,8-connected
csq
net)
form
hierarchical
mesoporous
sizes
up
6.7
nm;
(2)
Zr6
clusters
tetracarboxylates
NU-1100
series
(4,12-connected
ftw
4300–6500
g–1;
(3)
use
hexacarboxylates
combination
results
formation
NU-1600
6,12-connected
alb
2000–4500
g–1.
Third,
exploration
access
uranium-based
MOFs,
NU-1300
3,4-connected
tbo
2100
g–1)
NU-1301
3-connected
nun
4750
g–1).
investigated
structurally
complex
NU-1301,
formed
serendipitously
uranyl
triangular
carboxylates
structure
largest
unit
cell
all
reported
MOFs.Finally,
provide
overview
potential
water
capture,
storage,
separation
dyes
biological
macromolecules.
We
hope
Account
may
serve
blueprint
stimulate
researchers
develop
next
generation
energy-
environment-related
beyond.
