Chemical Science,
Journal Year:
2021,
Volume and Issue:
12(20), P. 6772 - 6799
Published: Jan. 1, 2021
MOFs
are
promising
candidates
for
the
capture
of
toxic
gases
such
as
SO2,
H2S,
NH3
and
NOx.
Understanding
role
different
chemical
functionalities,
within
pores
MOFs,
is
key
accomplishing
superior
captures
these
gases.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(3), P. 4163 - 4203
Published: Jan. 19, 2022
The
crystal–liquid–glass
phase
transition
of
coordination
polymers
(CPs)
and
metal–organic
frameworks
(MOFs)
offers
attractive
opportunities
as
a
new
class
amorphous
materials.
Unlike
conventional
glasses,
chemistry
allows
the
utilization
rational
design
concepts
to
fine-tune
desired
properties.
Although
glassy
state
has
been
rare
in
CPs/MOFs,
it
exhibits
diverse
advantages
complementary
their
crystalline
counterparts,
including
improved
mass
transport,
optical
properties,
mechanical
ability
form
grain-boundary-free
monoliths.
This
Review
discusses
current
achievements
improving
understanding
anomalous
transitions
CPs/MOFs.
We
elaborate
on
criteria
for
classifying
CP/MOF
glasses
comprehensively
discuss
three
common
strategies
employed
obtain
state.
include
all
glass
research
progress
since
its
inception,
challenges,
express
our
perspective
future
directions.
Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
123(16), P. 10432 - 10467
Published: July 14, 2023
Metal–organic
frameworks
(MOFs)
and
ionic
liquids
(ILs)
represent
promising
materials
for
adsorption
separation.
ILs
incorporated
into
MOF
(denoted
as
IL/MOF
composites)
have
been
developed,
composites
combine
the
advantages
of
MOFs
to
achieve
enhanced
performance
in
adsorption-based
separation
fluid
mixtures.
The
designed
different
are
introduced
various
tailor
their
functional
properties,
which
affect
optimal
adsorptive
performance.
In
this
Perspective,
rational
fabrication
is
presented,
properties
demonstrated.
This
paper
provides
a
critical
overview
an
emergent
class
termed
well
recent
advances
applications
adsorbents
or
membranes
Furthermore,
gas
separations
(CO2
capture
from
flue
gas,
natural
purification,
acetylene
ethylene,
indoor
pollutants
removal)
liquid
(separation
bioactive
components,
organic-contaminant
removal,
desulfurization,
radionuclide
discussed.
Finally,
existing
challenges
highlighted,
appropriate
design
strategy
direction
effective
exploration
new
proposed.
ACS Applied Materials & Interfaces,
Journal Year:
2022,
Volume and Issue:
14(8), P. 9970 - 9986
Published: Feb. 17, 2022
The
development
of
materials
with
outstanding
performance
for
sensitive
and
selective
detection
multiple
analytes
is
essential
the
human
health
society.
Luminescent
metal-organic
frameworks
(LMOFs)
have
controllable
surface
pore
sizes
excellent
optical
properties.
Therefore,
a
variety
LMOF-based
sensors
diverse
functions
can
be
easily
designed
applied.
Furthermore,
introduction
energy
transfer
(ET)
into
LMOFs
(ET-LMOFs)
could
provide
richer
design
concept
much
more
accurate
sensing
performance.
In
this
review,
we
focus
on
recent
five
years
advances
in
ET-LMOF-based
materials,
an
emphasis
photochemical
photophysical
mechanisms.
We
discuss
detail
possible
processes
within
MOF
structure
or
between
MOFs
guest
materials.
Finally,
applications
are
highlighted.
Journal of Hazardous Materials,
Journal Year:
2022,
Volume and Issue:
442, P. 130127 - 130127
Published: Oct. 7, 2022
The
presence
of
persistent
organic
pollutants
(POPs)
in
the
aquatic
environment
is
causing
widespread
concern
due
to
their
bioaccumulation,
toxicity,
and
possible
environmental
risk.
These
contaminants
are
produced
daily
large
quantities
released
into
water
bodies.
Traditional
wastewater
treatment
plants
ineffective
at
degrading
these
pollutants.
As
a
result,
development
long-term
effective
POP
removal
techniques
critical.
In
water,
adsorption
photocatalytic
degradation
POPs
have
been
identified
as
energy
cost-efficient
solutions.
Both
technologies
received
lot
attention
for
efforts
treat
world's
wastewater.
Photocatalytic
promising,
effective,
long-lasting
method,
while
represents
simple,
practical
particularly
decentralized
systems
isolated
areas.
It
critical
develop
new
adsorbents/photocatalysts
with
desired
structure,
tunable
chemistry,
maximum
sites
highly
efficient
POPs.
class
recently
created
multifunctional
porous
materials,
Metal-organic
frameworks
(MOFs)
offer
tremendous
prospects
adsorptive
remediation.
This
review
defines
discusses
current
research
on
using
emerging
MOFs
each
type
Advances in Colloid and Interface Science,
Journal Year:
2023,
Volume and Issue:
314, P. 102864 - 102864
Published: Feb. 26, 2023
Designable
morphology
and
predictable
properties
are
the
most
challenging
goals
in
material
engineering.
Features
such
as
shape,
size,
porosity,
agglomeration
ratio
significantly
affect
final
of
metal-organic
frameworks
(MOFs)
can
be
regulated
throughout
synthesis
parameters
but
require
a
deep
understanding
mechanisms
MOFs
formation.
Herein,
we
systematically
summarize
effects
individual
factors,
pH
reaction
mixture,
including
acidic
or
basic
character
modulators,
temperature,
solvents
types,
surfactants
type
content
ionic
liquids
on
growing
MOFs.
We
identified
main
MOFs'
growth
leading
to
different
particles
next
discuss
effect
miscellaneous
based
related
nucleation,
formation
structure,
coordination
modulation,
protonation/deprotonation
acting
modulation
by
capping
agents.
The
microwaves
ultrasound
employment
during
is
also
considered
due
their
affecting
especially
nucleation
steps
Angewandte Chemie International Edition,
Journal Year:
2021,
Volume and Issue:
60(33), P. 17998 - 18005
Published: June 15, 2021
Herein,
we
report
a
pre-synthetic
pore
environment
design
strategy
to
achieve
stable
methyl-functionalized
metal-organic
frameworks
(MOFs)
for
preferential
SO
