Capture of toxic gases in MOFs: SO2, H2S, NH3 and NOx DOI Creative Commons

Eva Martínez‐Ahumada,

Mariana L. Díaz‐Ramírez, Miriam De J. Velásquez-Hernández

et al.

Chemical Science, Journal Year: 2021, Volume and Issue: 12(20), P. 6772 - 6799

Published: Jan. 1, 2021

MOFs are promising candidates for the capture of toxic gases such as SO2, H2S, NH3 and NOx. Understanding role different chemical functionalities, within pores MOFs, is key accomplishing superior captures these gases.

Language: Английский

Recent advances in metal–organic frameworks for gas adsorption/separation DOI Creative Commons

Chuanhai Jiang,

Xiaokang Wang,

Yuguo Ouyang

et al.

Nanoscale Advances, Journal Year: 2022, Volume and Issue: 4(9), P. 2077 - 2089

Published: Jan. 1, 2022

This review summarizes the representative works of MOFs for gas adsorption/separation in recent years, analyses host–guest interaction, structure–performance relations, and mechanism.

Language: Английский

Citations

131
Contribution of hydrogen bonding to liquid-phase adsorptive removal of hazardous organics with metal-organic framework-based materials DOI
Imteaz Ahmed, Zubair Hasan, Gyudong Lee

et al.

Chemical Engineering Journal, Journal Year: 2021, Volume and Issue: 430, P. 132596 - 132596

Published: Sept. 24, 2021

Language: Английский

Citations

128
Polyoxometalate-based metal–organic frameworks for heterogeneous catalysis DOI
Shaowei Zhang,

Fuxia Ou,

Shiggang Ning

et al.

Inorganic Chemistry Frontiers, Journal Year: 2021, Volume and Issue: 8(7), P. 1865 - 1899

Published: Jan. 1, 2021

POM-based MOFs simultaneously possessing the virtues of POMs and exhibit excellent heterogeneous catalytic properties.

Language: Английский

Citations

124
Optimal Pore Chemistry in an Ultramicroporous Metal–Organic Framework for Benchmark Inverse CO2/C2H2 Separation DOI
Zhaoqiang Zhang, Shing Bo Peh, Rajamani Krishna

et al.

Angewandte Chemie International Edition, Journal Year: 2021, Volume and Issue: 60(31), P. 17198 - 17204

Published: May 27, 2021

Abstract Isolation of CO 2 from acetylene (C H ) via ‐selective sorbents is an energy‐efficient technology for C purification, but a strategic challenge due to their similar physicochemical properties. There still no specific methodology constructing that preferentially trap over . We report effective strategy construct optimal pore chemistry in Ce IV ‐based ultramicroporous metal–organic framework ‐MIL‐140‐4F, based on charge‐transfer effects, efficient inverse /C separation. The ligand‐to‐metal cluster charge transfer facilitated by with low‐lying unoccupied 4f orbitals and electron‐withdrawing F atoms functionalized tetrafluoroterephthalate, affording perfect environment match exceptional uptake (151.7 cm 3 −3 along remarkable separation selectivities (above 40) set new benchmark separation, which verified simulated experimental breakthrough experiments. unique recognition mechanism further unveiled situ powder X‐ray diffraction experiments, Fourier‐transform infrared spectroscopy measurements, molecular calculations.

Language: Английский

Citations

124
Capture of toxic gases in MOFs: SO2, H2S, NH3 and NOx DOI Creative Commons

Eva Martínez‐Ahumada,

Mariana L. Díaz‐Ramírez, Miriam De J. Velásquez-Hernández

et al.

Chemical Science, Journal Year: 2021, Volume and Issue: 12(20), P. 6772 - 6799

Published: Jan. 1, 2021

MOFs are promising candidates for the capture of toxic gases such as SO2, H2S, NH3 and NOx. Understanding role different chemical functionalities, within pores MOFs, is key accomplishing superior captures these gases.

Language: Английский

Citations

123