A self-regenerating Pt/Ge-MFI zeolite for propane dehydrogenation with high endurance
He Hong,
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Zhikang Xu,
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Bingbao Mei
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et al.
Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 10, 2025
Supported
noble
metal
cluster
catalysts
are
typically
operated
under
severe
conditions
involving
switches
between
reducing
and
oxidizing
atmospheres,
causing
irreversible
transformation
of
catalyst
structure
thereby
leading
to
permanent
deactivation.
We
discovered
that
various
Pt
precursors
spontaneously
disperse
in
Ge-MFI
zeolite,
which
opposes
the
Ostwald
ripening
phenomenon,
producing
self-regenerating
Pt/Ge-MFI
for
propane
dehydrogenation.
These
reversibly
switch
clusters
single-atoms
response
reaction
regeneration
conditions.
This
environmental
adaptability
allows
them
completely
self-regenerate
over
110
reaction-regeneration
cycles
They
exhibited
unprecedented
sintering-resistance
when
exposed
air
at
800
°C
10
days.
Such
spontaneous
dispersion
Ge-zeolites
is
a
robust
versatile
methodology
fabricating
Rh,
Ru,
Ir
Pd
catalysts.
Language: Английский
Optimized Pt Loaded Cerium Tungstate Electrochemical Sensor for Rapid Response and Recovery NO2 Detection
Jiaxin Li,
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Xichao Mo,
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Chonghui Zhu
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et al.
Advanced Sensor Research,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 23, 2025
Abstract
Nitrogen
dioxide
(NO
2
)
is
a
dangerous
environmental
pollutant
that
poses
risk
to
human
health
and
ecosystems,
leading
respiratory
disease
degradation.
Current
detection
methods
often
suffer
from
high
power
consumption,
sensitivity,
limited
stability.
In
this
study,
an
electrochemical
gas
sensor
synthesized
by
calcination
hydrothermal
method
presented
using
cerium
tungstate
(Ce
(WO
4
3
as
support
material
doped
with
0.5
wt.%
platinum
(Pt).
The
has
limit
low
ppm,
response
time
of
27.1
s,
recovery
7.9
s
at
room
temperature.
It
also
better
selectivity
for
NO
than
other
gases
good
humidity
resistance.
improved
sensing
performance
attributed
the
increase
in
oxygen
vacancy
concentration
favorable
interaction
between
Pt
Ce
,
which
promotes
active
site
formation
catalytic
efficiency.
These
results
highlight
potential
Pt/Ce
effective
energy‐efficient
detection,
providing
new
approach
real‐time
monitoring
fast
selectivity.
Language: Английский