Associations between Urinary Phthalate Metabolites with BDNF and Behavioral Function among European Children from Five HBM4EU Aligned Studies DOI Creative Commons
Elena Salamanca‐Fernández, Lydia Espín-Moreno, Alicia Olivas-Martínez

et al.

Toxics, Journal Year: 2024, Volume and Issue: 12(9), P. 642 - 642

Published: Aug. 31, 2024

Based on toxicological evidence, children’s exposure to phthalates may contribute altered neurodevelopment and abnormal regulation of brain-derived neurotrophic factor (BDNF). We analyzed data from five aligned studies the Human Biomonitoring for Europe (HBM4EU) project. Ten phthalate metabolites protein BDNF levels were measured in urine samples 1148 children aged 6–12 years Italy (NACII-IT cohort), Slovakia (PCB-SK Hungary (InAirQ-HU cohort) Norway (NEBII-NO). Serum was also available 124 Slovenian (CRP-SLO cohort). Children’s total, externalizing internalizing behavioral problems assessed using Child Behavior Checklist at 7 age (only NACII-IT Adjusted linear negative binomial regression models fitted, together with weighted quantile sum (WQS) assess mixture associations. Results showed that, boys but not girls cohort, each natural-log-unit increase mono-n-butyl (MnBP) Mono(2-ethyl-5-oxohexyl) (MEOHP) cross-sectionally associated higher [incidence rate ratio (IRR): 1.20; 95% CI: 1.02, 1.42 1.26; 1.03, 1.55, respectively]. A suggestive association observed per tertile whole population (WQS—IRR = 1.15; 0.97, 1.36) (IRR 0.96, 1.49). In NACII-IT, PCB-SK, InAirQ-HU NEBII-NO cohorts together, urinary strongly levels, WQS confirming a (percent change (PC) 25.9%; 17.6, 34.7), (PC 18.6%; 7.92, 30.5) mainly among 36.0%; 24.3, 48.9). Among CRP-SLO boys, ∑DINCH concentration lower serum (PC: −8.8%; −16.7, −0.3). predicted worse scores all (IRR: 1.00, 1.32). suggest that (1) di-n-butyl (DnBP) di(2-ethylhexyl) (DEHP) is more (2) DINCH associate systemic (3) concentrations (although caution needed since possibility “urine bias” could explain these associations noncausal terms identified) (4) predict problems. Given this first study examine relationship between metabolite biomarkers, future are validate

Language: Английский

Plastics can be used more sustainably in agriculture DOI Creative Commons
Thilo Hofmann, Subhasis Ghoshal, Nathalie Tufenkji

et al.

Communications Earth & Environment, Journal Year: 2023, Volume and Issue: 4(1)

Published: Sept. 25, 2023

Abstract Plastics have become an integral component in agricultural production as mulch films, nets, storage bins and many other applications, but their widespread use has led to the accumulation of large quantities soils. Rational reduction, collection, reuse, innovative recycling are key measures curb plastic pollution from agriculture. that cannot be collected after must biodegradable environmentally benign manner. Harmful additives replaced with safer alternatives reduce toxicity burdens included ongoing negotiations surrounding United Nations Treaty. Although full substitution plastics is currently not possible without increasing overall environmental footprint jeopardizing food security, smaller impacts should used endorsed within a clear socio-economic framework. Better monitoring reporting, technical innovation, education training, social economic incentives imperative promote more sustainable

Language: Английский

Citations

89
Global environmental and toxicological data of emerging plasticizers: current knowledge, regrettable substitution dilemma, green solution and future perspectives DOI
Abdul Qadeer, Muhammad Yunus Anis, Genoa R. Warner

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(10), P. 5635 - 5683

Published: Jan. 1, 2024

The global plasticizer market is projected to increase from $17 billion in 2022 $22.5 2027.

Language: Английский

Citations

35
Global environmental and toxicological impacts of polybrominated diphenyl ethers versus organophosphate esters: A comparative analysis and regrettable substitution dilemma DOI
Abdul Qadeer,

Sidra Mubeen,

Mengyang Liu

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 466, P. 133543 - 133543

Published: Jan. 17, 2024

Language: Английский

Citations

24
Metaheuristic optimization algorithms-based prediction modeling for titanium dioxide-Assisted photocatalytic degradation of air contaminants DOI Creative Commons

Muhammad Faisal Javed,

Bilal Siddiq,

Kennedy C. Onyelowe

et al.

Results in Engineering, Journal Year: 2024, Volume and Issue: 23, P. 102637 - 102637

Published: July 29, 2024

Airborne contaminants pose significant environmental and health challenges. Titanium dioxide (TiO2) has emerged as a leading photocatalyst in the degradation of air compared to other photocatalysts due its inherent inertness, cost-effectiveness, photostability. To assess effectiveness, laboratory examinations are frequently employed measure photocatalytic rate TiO2. However, this approach involves time-consuming requirements, labor-intensive tasks, high costs. In literature, ensemble or standalone models commonly used for assessing performance TiO2 water contaminants. Nonetheless, application metaheuristic hybrid potential be more effective predictive accuracy efficiency. Accordingly, research utilized machine learning (ML) algorithms estimate photo-degradation constants organic pollutants using nanoparticles exposure ultraviolet light. Six metaheuristics optimization algorithms, namely, nuclear reaction (NRO), differential evolution algorithm (DEA), human felicity (HFA), lightning search (LSA), Harris hawks (HHA), tunicate swarm (TSA) were combined with random forest (RF) technique establish models. A database 200 data points was acquired from experimental studies model training testing. Furthermore, multiple statistical indicators 10-fold cross-validation examine established model's robustness. The TSA-RF demonstrated superior prediction among six suggested models, achieving an impressive correlation (R) 0.90 lower root mean square error (RMSE) 0.25. contrast, HFA-RF, HHA-RF, NRO-RF exhibited slightly R-value 0.88, RMSE scores 0.32. DEA-RF LSA-RF while effective, showed marginally 0.85, values 0.45 0.44, respectively. Moreover, SHapley Additive exPlanation (SHAP) results indicated that rates through photocatalysis most notably influenced by factors such reactor sizes, dosage, humidity, intensity.

Language: Английский

Citations

20
Advancements in MXene-based frameworks towards photocatalytic hydrogen production, carbon dioxide reduction and pollutant degradation: Current challenges and future prospects DOI
Zeeshan Ajmal, Asif Hayat, Abdul Qadeer

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216226 - 216226

Published: Oct. 7, 2024

Language: Английский

Citations

18
Recent advances in COF-based framework: Synthesis, Potential application, Current challenges and Future direction DOI
Zeeshan Ajmal, Simon Kizito,

Basem Alalwan

et al.

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 39, P. 102140 - 102140

Published: June 13, 2024

Language: Английский

Citations

17
Legacy and Emerging Plasticizers and Stabilizers in PVC Floorings and Implications for Recycling DOI Creative Commons
Helene Wiesinger,

Christophe Bleuler,

Verena Christen

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(4), P. 1894 - 1907

Published: Jan. 19, 2024

Hazardous chemicals in building and construction plastics can lead to health risks due indoor exposure may contaminate recycled materials. We systematically sampled new polyvinyl chloride floorings on the Swiss market (

Language: Английский

Citations

16
Recent advancement in conjugated polymers based photocatalytic technology for air pollutants abatement: Cases of CO2, NOx, and VOCs DOI
Zeeshan Ajmal, Mahmood Ul Haq, Yassine Naciri

et al.

Chemosphere, Journal Year: 2022, Volume and Issue: 308, P. 136358 - 136358

Published: Sept. 7, 2022

Language: Английский

Citations

65
Nanostructured materials based on g-C3N4 for enhanced photocatalytic activity and potentials application: A review DOI Creative Commons
Muhammad Sohail, Usama Anwar, T.A. Taha

et al.

Arabian Journal of Chemistry, Journal Year: 2022, Volume and Issue: 15(9), P. 104070 - 104070

Published: July 2, 2022

Semiconductor-based photocatalytic technology is regarded as an efficient pathway for resolving the energy scarcity across globe. In this regard, graphitic carbon nitride (g-C3N4)-based materials could be alternatively employed in photochemical applications such photovoltaic generation via CO2 photoreduction and water splitting, along with natural resource purification organic/inorganic pollutant degradation. Indeed, kind of assertion has been made by considering intrinsic physicochemical properties g-C3N4 nanomaterials, owing to their increased surface area, quantum yield, charge isolation, distribution, ease modification through material configuration or incorporation preferred interfacial capabilities. This review article designed provide most up-to-date information regarding further assessment important advancements fabrication various while specifically focusing on scientific reason behind its success each assessment. The discovery interventions alleviate restrictions boost performance gained substantial interest. Following photo-excitation fundamentals, work explains two distinct photoexcitation mechanisms, carrier transfer techniques, wherein significant exciting state impact still not widely focused past studies. regards, we cautiously introduce updated advances associated functions alteration including morphological features, elemental dopants, deficiency engineering, heterojunction implemented performance, which are equated from transport perceptions. future perspectives designing properly tuning highly active hierarchical copolymer nanoparticles a system, may improve renewable cultivation reduction efficiency critically deciphered detail outlined thoroughly.

Language: Английский

Citations

55
Recent Advances and Future Perspectives of Metal‐Based Electrocatalysts for Overall Electrochemical Water Splitting DOI
Asif Hayat, Muhammad Sohail,

Hamid Ali

et al.

The Chemical Record, Journal Year: 2022, Volume and Issue: 23(2)

Published: Nov. 21, 2022

Abstract Recently, the growing demand for a renewable and sustainable fuel alternative is contingent on cell technologies. Even though it regarded as an environmentally method of generating immediate concerns, must be enhanced to make extraordinarily affordable, sustainable. Hydrogen (H 2 ) synthesis by electrochemical water splitting (ECWS) considered one foremost potential prospective methods energy output H society implementation. Existing massive mostly reliant steaming reformation carbon fuels that yield CO together with finite resource. ECWS viable, efficient, contamination‐free evolution. Consequently, developing reliable cost‐effective technology was top priority scientists around globe. Utilizing technologies decrease total utilization crucial Capturing transforming from ambient through various solutions (WS) could effectively reduce need additional electricity. among achievement ‐based economy. For overall (OWS), several transition‐metal‐based polyfunctional metal catalysts both cathode anode have been synthesized. Furthermore, essential widespread adoption such development reduced‐price, super functional electrocatalysts substitute those, depending metals. Many metal‐premised designed WS process. The attributes oxygen (O dynamics interactions electrodes electrolysis cells fundamental techniques evaluating are outlined in this paper. Special emphasis paid their fabrication, electrocatalytic performance, durability, measures enhancing efficiency. In addition, ideas metal‐based based existing problems presented. It anticipated review will offer straight direction toward engineering construction novel encompassing superior efficiency suitable technique.

Language: Английский

Citations

53