Molecular Design of the Polyamide Layer Structure of Nanofiltration Membranes by Sacrificing Hydrolyzable Groups toward Enhanced Separation Performance DOI
Kunpeng Wang, Wenjie Fu, Xiaomao Wang

et al.

Environmental Science & Technology, Journal Year: 2022, Volume and Issue: 56(24), P. 17955 - 17964

Published: Nov. 29, 2022

Nanofiltration (NF) is an effective technology for removing trace organic contaminants (TrOCs), while the inherent trade-off effect between water permeance and solute rejections hinders its widespread application in treatment. Herein, we propose a novel scheme of "monomers with sacrificial groups" to regulate microstructure polyamide active layer via introducing hydrolyzable ester group onto piperazine control diffusion interfacial polymerization process. The achieved benefits include narrowing pore size, improving interpore connectivity, enhancing microporosity, reducing thickness, which collectively realized simultaneous improvement enhancement TrOCs rejection performance. resulting membranes were superior both commercial membranes, especially water-TrOCs selectivity. effects using new monomers on membrane physicochemical properties systematically studied, underlying mechanisms enhanced separation performance further revealed by simulating process through density functional theory calculation measuring trans-interface rate monomers. This study demonstrates promising NF synthesis strategy designing structure reaction achieving excellent low energy input

Language: Английский

Nano-wrinkled polyamide membrane preparation via heterogeneous surface-regulated interfacial polymerization for enhanced desalination performance DOI
Zhiwen Li, Yanchao Xu, Liguo Shen

et al.

Desalination, Journal Year: 2023, Volume and Issue: 564, P. 116801 - 116801

Published: June 29, 2023

Language: Английский

Citations

15
Mechanistic insights into the separation behaviors of polyamide desalination membranes for emerging micropollutants removal DOI
Fuxin Zheng,

Tiange Yan,

Yalong Lei

et al.

Journal of Membrane Science, Journal Year: 2024, Volume and Issue: 709, P. 123101 - 123101

Published: July 17, 2024

Language: Английский

Citations

5
High-Performance Nanofiltration Membrane with Dual Resistance to Gypsum Scaling and Biofouling for Enhanced Water Purification DOI
Fuxin Zheng, Hao Zhang, Chanhee Boo

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(37), P. 16656 - 16668

Published: Sept. 2, 2024

Nanofiltration (NF) technology is pivotal for ensuring a sustainable and reliable supply of clean water. To address the critical need advanced thin-film composite (TFC) polyamide (PA) membranes with exceptional permselectivity fouling resistance emerging contaminant purification, we introduce novel high-performance NF membrane. This membrane features selective polypiperazine (PIP) layer functionalized amino-containing quaternary ammonium compounds (QACs) through an

Language: Английский

Citations

5
Machine Learning-Aided Inverse Design and Discovery of Novel Polymeric Materials for Membrane Separation DOI Creative Commons

Raghav Dangayach,

Nohyeong Jeong, Elif Demirel

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

Polymeric membranes have been widely used for liquid and gas separation in various industrial applications over the past few decades because of their exceptional versatility high tunability. Traditional trial-and-error methods material synthesis are inadequate to meet growing demands high-performance membranes. Machine learning (ML) has demonstrated huge potential accelerate design discovery membrane materials. In this review, we cover strengths weaknesses traditional methods, followed by a discussion on emergence ML developing advanced polymeric We describe methodologies data collection, preparation, commonly models, explainable artificial intelligence (XAI) tools implemented research. Furthermore, explain experimental computational validation steps verify results provided these models. Subsequently, showcase successful case studies emphasize inverse methodology within ML-driven structured framework. Finally, conclude highlighting recent progress, challenges, future research directions advance next generation With aim provide comprehensive guideline researchers, scientists, engineers assisting implementation process.

Language: Английский

Citations

5
Molecular Design of the Polyamide Layer Structure of Nanofiltration Membranes by Sacrificing Hydrolyzable Groups toward Enhanced Separation Performance DOI
Kunpeng Wang, Wenjie Fu, Xiaomao Wang

et al.

Environmental Science & Technology, Journal Year: 2022, Volume and Issue: 56(24), P. 17955 - 17964

Published: Nov. 29, 2022

Nanofiltration (NF) is an effective technology for removing trace organic contaminants (TrOCs), while the inherent trade-off effect between water permeance and solute rejections hinders its widespread application in treatment. Herein, we propose a novel scheme of "monomers with sacrificial groups" to regulate microstructure polyamide active layer via introducing hydrolyzable ester group onto piperazine control diffusion interfacial polymerization process. The achieved benefits include narrowing pore size, improving interpore connectivity, enhancing microporosity, reducing thickness, which collectively realized simultaneous improvement enhancement TrOCs rejection performance. resulting membranes were superior both commercial membranes, especially water-TrOCs selectivity. effects using new monomers on membrane physicochemical properties systematically studied, underlying mechanisms enhanced separation performance further revealed by simulating process through density functional theory calculation measuring trans-interface rate monomers. This study demonstrates promising NF synthesis strategy designing structure reaction achieving excellent low energy input

Language: Английский

Citations

19