Facile and rapid preparation of magnetic imprinted adsorbent for specific separation and capture of liquid-crystal monomers pollutants in environmental water and soil samples DOI Creative Commons

Yueyue Zhang,

Dingliang Tang,

Yuanfei Wu

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 15, 2024

Abstract Specific separation and extraction is a pivotal stage in the accurate quantification of liquid crystal monomers (LCMs) pollutants complex environmental samples. In this context, new fluorinated imprinted adsorbent (MIA) for magnetic solid phase (MSPE) was one-pot prepared within 3.5 h using 4-[difluoro(3,4,5-trifluorophenoxy)methyl]-3,5-difluoro-4'-ethyl-biphenyl (DFBP) as template 1H,1H,2H,2H-heptadecafluorodecyl acrylate/vinylanthracene dual monomers. The structure, morphology properties MIA fabricated beneficial conditions were investigated by various characterized techniques. Under optimal parameters, presented satisfactory specific recognition performance. factor adsorption capacity towards DFBP high 2.7 15.9 mg/g, respectively. At same time, behaviors MIA/MSPE surveyed means kinetics isotherm. Combining with HPLC coupled diode array detector (DAD), sensitive, reliable anti-interference method monitoring LCMs residuals water soil samples established. achieved enrichment factors 132–248 96–204 samples, corresponding limits detection 0.0017–0.0051 µg/L 0.087–0.28 µg/kg, Moreover, confirmatory experiments adopted to inspect accuracy established MIA/MSPE-HPLC/DAD approach. To best our knowledge, first time that material isolation capture which have been classified emerging organic pollutants.

Language: Английский

Integrative molecular and physiological insights into the phytotoxic impact of liquid crystal monomer exposure and the protective strategy in plants DOI Creative Commons
Dong Jiang, Guoqun Yang, Lijun Huang

et al.

Plant Biotechnology Journal, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 11, 2025

Summary Liquid crystal monomers (LCMs), the integral components in manufacture of digital displays, have engendered environmental concerns due to extensive utilization and intensive emission. Despite their prevalence ecotoxicity, LCM impacts on plant growth agricultural yield remain inadequately understood. In this study, we investigated specific response mechanisms tobacco, a pivotal crop model plant, four representative LCMs (2OdF3B, 5CB, 4PiMeOP, 2BzoCP) through integrative molecular physiological approaches. The findings reveal impacts, with 4PiMeOP exerting most pronounced effects, followed by 2BzoCP, 2OdF3B. exposure disrupts photosynthetic apparatus, exacerbating reactive oxygen species (ROS) levels leaves, which turn triggers upregulation antioxidative enzymes synthesis antioxidant substances. Additionally, strongly stimulate expression genes involved abscisic acid (ABA) biosynthesis signalling pathways. AI‐assisted meta‐analysis implicates ABA as critical regulator tobacco LCMs. Notably, exogenous application alleviates LCM‐induced toxicities, highlighting role stress amelioration. Our study provides novel insights into toxicity tolerance plants, shedding light both harmful effects ecosystems potential adaptation responses. This is crucial develop sustainable systems reducing negative caused emerging organic pollutants.

Language: Английский

Citations

0
Critical assessment of quenching and extraction/sample preparation methods for microorganisms in metabolomics DOI
Hossein Sedighikamal, Shohreh Mashayekhan

Metabolomics, Journal Year: 2025, Volume and Issue: 21(2)

Published: March 13, 2025

Language: Английский

Citations

0
Hepatotoxicity of Three Common Liquid Crystal Monomers in Mus musculus: Differentiation of Actions Across Different Receptors and Pathways DOI
Zhichao Zhang, Shengjie Yuan,

Zhongchao Yang

et al.

Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

Liquid crystal monomers (LCMs) of different chemical structures were widely detected in various environmental matrices. However, their health risk evaluation is lacking. Herein, three representative LCMs selected from 74 LCM candidates upon literature review and acute cytotoxicity evaluation, then Mus musculus exposed to the for 42 days at doses 0.5 50 μg/kg/d investigate hepatotoxicity mechanisms. Phenotypic histopathological results showed that (DTMDPB, MeO3bcH, 5OCB) induced hepatomegaly, only 5OCB fatty liver. DTMDPB MeO3bcH decreased total cholesterol (TCHO) triglyceride (TG) content, whereas increased TCHO, TG, alanine aminotransferase levels. Transcriptome molecular docking analysis revealed by agonizing farnesoid X receptor, resulting disruption unsaturated acid biosynthesis, ascorbic antioxidant pathways, circadian clock homeostasis. promoted inflammation altered acid, primary bile rhythm antagonizing aryl hydrocarbon receptor. antagonized peroxisome proliferator-activated receptors, leading liver caused steroid, cholesterol, terpenoid backbone biosynthesis pathways. This study provides references understanding with selection priority control LCMs.

Language: Английский

Citations

0
Facile and rapid preparation of magnetic imprinted adsorbent for specific separation and capture of liquid-crystal monomers pollutants in environmental water and soil samples DOI Creative Commons

Yueyue Zhang,

Dingliang Tang,

Yuanfei Wu

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 15, 2024

Abstract Specific separation and extraction is a pivotal stage in the accurate quantification of liquid crystal monomers (LCMs) pollutants complex environmental samples. In this context, new fluorinated imprinted adsorbent (MIA) for magnetic solid phase (MSPE) was one-pot prepared within 3.5 h using 4-[difluoro(3,4,5-trifluorophenoxy)methyl]-3,5-difluoro-4'-ethyl-biphenyl (DFBP) as template 1H,1H,2H,2H-heptadecafluorodecyl acrylate/vinylanthracene dual monomers. The structure, morphology properties MIA fabricated beneficial conditions were investigated by various characterized techniques. Under optimal parameters, presented satisfactory specific recognition performance. factor adsorption capacity towards DFBP high 2.7 15.9 mg/g, respectively. At same time, behaviors MIA/MSPE surveyed means kinetics isotherm. Combining with HPLC coupled diode array detector (DAD), sensitive, reliable anti-interference method monitoring LCMs residuals water soil samples established. achieved enrichment factors 132–248 96–204 samples, corresponding limits detection 0.0017–0.0051 µg/L 0.087–0.28 µg/kg, Moreover, confirmatory experiments adopted to inspect accuracy established MIA/MSPE-HPLC/DAD approach. To best our knowledge, first time that material isolation capture which have been classified emerging organic pollutants.

Language: Английский

Citations

0