Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: 155, P. 858 - 888
Published: Nov. 9, 2024
Language: Английский
Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: 155, P. 858 - 888
Published: Nov. 9, 2024
Language: Английский
Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 137423 - 137423
Published: Jan. 1, 2025
Language: Английский
Citations
4Published: March 4, 2025
Language: Английский
Citations
4Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(36), P. 16215 - 16224
Published: Aug. 27, 2024
Elimination of dilute gaseous toluene is one the critical concerns within field indoor air remediation. The typical degradation route on titanium-based catalysts, "toluene-benzaldehyde-carbon dioxide", necessitates oxidation methyl group as a prerequisite for photocatalytic oxidation. However, inherent planar adsorption configuration molecules, dominated by benzene rings, leads to significant steric hindrance group. This prevents from contacting active species catalyst surface, thereby limiting removal under conditions. To date, no effective strategy control has been identified. Herein, we showed B-Ti-O interface that exhibits significantly enhanced efficiency In-depth investigations revealed that, compared Ti-based photocatalysts, between and surface decreased 3.42 3.03 Å designed interface. reduction originates matching orbital energy levels Ti 3d
Language: Английский
Citations
5Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 359, P. 124510 - 124510
Published: Aug. 15, 2024
Language: Английский
Citations
4ACS ES&T Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 21, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: March 3, 2025
Abstract Replacing fossil fuels by renewable biomass enables green syngas production in an effort to achieve carbon neutrality and sustainable circular processes. Here, inexpensive catalyst of Ni nanoparticles supported on SiO 2 modified La 3+ (Ni/La 0.10 –S) is presented, exhibiting exceptional H CO rates (4051.4 2467.8 mmol g −1 h , respectively) with 7.7% light‐to‐fuel efficiency cellulose steam reforming (SR), merely under focused illumination. Excellent performance mainly attributed photothermal catalysis resulting from the strong solar absorption high conversion nanoparticles. The mitigation tar char formation significantly benefits O involvement reaction, which substantially improved addition enhancing sorption. Remarkably, illumination exerts mere photoactivation during primarily pronounced activation Ni─O bonds at surface. Particularly, Ni–O–La moieties, combination species replenishment O, makes Ni/La –S superior Ni/SiO . synergy promotion Ni–O poses a promising strategy for efficient catalytic SR syngas.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125253 - 125253
Published: March 1, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
The complete catalytic oxidation of propane (C3H8) at low temperatures remains challenging due to the competitive adsorption between O2 and C3H8 molecules. In this study, we propose an innovative approach enhance by strategically designing active Ptδ+ sites with modulated electronic structures on F-doped TiO2-supported Pt catalyst (Pt/F-TiO2), which exhibits 50 90% conversion 200 320 °C. Our mechanistic study reveals that electron coupling 5d F 2p alters d orbital property, leads generation abundant efficient electron-enriched species. These new facilitate promote activation chemisorbed into superoxide species, in form bridge Pt-(O–O)ad-Ti, synergistically facilitates methyl C–H cleavage C3H8. This presents strategy for structure engineering Pt-based catalysts, paving way development high-performance catalysts oxidation.
Language: Английский
Citations
0Molecular Catalysis, Journal Year: 2025, Volume and Issue: 579, P. 115095 - 115095
Published: April 6, 2025
Language: Английский
Citations
0Journal of Catalysis, Journal Year: 2024, Volume and Issue: 440, P. 115846 - 115846
Published: Nov. 13, 2024
Language: Английский
Citations
2