For
several
decades,
the
methodology
of
complete
destruction
organic
pollutants
via
oxidation,
i.e.,
mineralization,
has
been
rooted
in
real
water
treatment
applications.
Nevertheless,
this
industrially
accepted
protocol
is
far
from
sustainable
because
excessive
input
chemicals
and/or
energy
as
well
unregulated
carbon
emission.
Recently,
there
have
emerging
studies
on
removal
a
completely
different
pathway,
polymerization,
meaning
that
target
undergo
oxidative
polymerization
reactions
to
generate
polymeric
products.
These
collectively
shown
compared
conventional
mineralization
pathway
allows
more
efficient
pollutants,
largely
reduced
chemicals,
and
suppressed
In
review,
we
aim
provide
comprehensive
examination
fundamentals
process,
current
state-of-the-art
strategies
for
regulation
both
kinetic
thermodynamic
perspectives,
resource
recovery
formed
end,
limitations
process
pollutant
are
discussed,
with
perspectives
future
studies.
Hopefully,
review
could
not
only
critical
insight
advancement
polymerization-oriented
technologies
greener
manner
but
also
stimulate
paradigm
innovations
low-carbon
treatment.
Environmental Science & Technology,
Journal Year:
2024,
Volume and Issue:
58(42), P. 18496 - 18507
Published: Oct. 9, 2024
Advanced
oxidation
processes
(AOPs)
are
rapidly
evolving
but
still
lack
well-established
protocols
for
reliably
identifying
oxidative
reactive
species
(ORSs).
This
Perspective
presents
both
the
radical
and
nonradical
ORSs
that
have
been
identified
or
proposed,
along
with
extensive
controversies
surrounding
mechanisms.
Conventional
identification
tools,
such
as
quenchers,
probes,
spin
trappers,
might
be
inadequate
analytical
demands
of
systems
in
which
multiple
coexist,
often
yielding
misleading
results.
Therefore,
challenges
these
complex,
short-lived,
transient
must
fully
acknowledged.
Refining
methods
is
necessary,
supported
by
rigorous
experiments
innovative
paradigms,
particularly
through
kinetic
analysis
based
on
situ
spectroscopic
techniques
multiple-probe
strategies.
To
demystify
complex
ORSs,
future
efforts
should
made
to
develop
advanced
tools
strategies
enhance
mechanism
understanding.
In
addition,
integrating
real-world
conditions
into
experimental
designs
will
establish
a
reliable
framework
fundamental
studies,
providing
more
accurate
insights
effectively
guiding
design
AOPs.
Langmuir,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 3, 2025
Advanced
oxidation
technology
plays
an
important
role
in
wastewater
treatment
due
to
active
substances
with
high
redox
potential.
Biochar
is
a
versatile
and
functional
biomass
material.
It
can
be
used
for
resource
management
of
various
waste
biomasses.
In
addition,
carbonaceous
materials
are
commonly
enhance
the
synergistic
mechanisms
advanced
processes,
because
their
good
electrical
conductivity
metal-free
leaching.
produced
from
through
pyrolysis
has
catalytic
potential,
cost-effective,
environmentally
friendly.
activate
hydrogen
peroxide,
persulfate,
ozone,
photocatalysis,
other
systems
degrading
organic
pollutants
water.
This
review
provides
summary
feedstocks,
conditions,
modification
methods
biochar
production.
also
described
effects
these
factors
on
yield,
structure,
sites
biochar.
The
summarized
applications
decontamination,
as
well
potential
practical
application.
Eventually,
limitations
this
current
technique
outlook
future
research
were
noted.
