Facile synthesis of fumarate-type iron-cobalt bimetallic MOFs and its application in photo-Fenton degradation of organic dyes DOI
Haohao Wang, Shouwu Yu, Xianguang Meng

et al.

Journal of Solid State Chemistry, Journal Year: 2022, Volume and Issue: 314, P. 123431 - 123431

Published: July 16, 2022

Language: Английский

Non-Calcined Layer-Pillared Mn0.5Zn0.5 Bimetallic–Organic Framework as a Promising Electrocatalyst for Oxygen Evolution Reaction DOI Creative Commons

Reza Abazari,

Ali Reza Amani‐Ghadim, Alexandra M. Z. Slawin

et al.

Inorganic Chemistry, Journal Year: 2022, Volume and Issue: 61(25), P. 9514 - 9522

Published: June 14, 2022

Electrocatalytic generation of oxygen is great significance for sustainable, clean, and efficient energy production. Multiple electron transfer in evolution reaction (OER) its slow kinetics represent a serious hedge water splitting, requiring the design development advanced electrocatalysts with porous structures, high surface areas, abundant electroactive sites, low overpotentials. These requisites are common metal-organic frameworks (MOFs) derived materials that promising OER. The present work reports on synthesis full characterization heteroleptic 3D MOF, [Zn2(μ4-odba)2(μ-bpdh)]n·nDMF (Zn-MUM-1), assembled from 4,4'-oxydibenzoic acid 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (bpdh). Besides, series heterometallic MnZn-MUM-1 (abbreviated as Mn0.5Zn0.5-MUM-1, Mn0.66Zn0.33-MUM-1, Mn0.33Zn0.66-MUM-1) was also prepared, characterized, used fabrication working electrodes based Ni foam (NF), followed by their exploration noble-metal-free robust stable do not require pyrolysis or calcination while exhibiting better electrocatalytic performance than parent Zn-MUM-1/NF electrode. experimental results show Mn0.5Zn0.5-MUM-1/NF electrocatalyst features best OER activity overpotential (253 mV at 10 mA cm-2) Tafel slope (73 dec-1) well significant stability after 72 h 6000 cycles. excellent explained synergic effect two different metals Mn-Zn MOF improved charge ion transfer, conductivity, characteristics. study thus widens application MOFs prospective highly

Language: Английский

Citations

75
In Situ Growth and Dynamic Transformation of Nickel Chelate Nanoarrays into Reactive Surface Reconstituted Heterostructure for Overall Water Splitting DOI Creative Commons

Qixiang Huang,

Fang Wang, Zixu Sun

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(46)

Published: June 25, 2024

Abstract In this work, self‐derivation and surface reconstruction strategies are innovatively introduced into the synthetic route of metal complex‐derived catalysts. The in situ grown nanorod arrays Ni‐based complex prepared by a simple rapid ligand chelation reaction. Furthermore, highly active heterogeneous electrocatalysts developed mild‐temperature calcination. Attributed to maintained morphology dispersed Ni/Ni(OH) 2 heterojunction sites, as‐prepared electrode exhibits superior hydrogen evolution activity (38.4 mV–10 mA cm −2 ). particular, dynamic during oxygen through Fourier transform infrared Raman spectroscopies observed. reconstructed Ni(OH) /NiOOH activation gives higher performance (369 mV–200 Further density functional theory mechanism studies disclose that contributes adsorption H* activated optimizes formation intermediates evolution.

Language: Английский

Citations

22
Concepts, fabrication and applications of MOF thin films in optoelectronics: A review DOI
Mohammad Mehdi Sabzehmeidani,

Shadi Gafari,

Sara jamali

et al.

Applied Materials Today, Journal Year: 2024, Volume and Issue: 38, P. 102153 - 102153

Published: March 28, 2024

Language: Английский

Citations

20
Metal organic frameworks (MOFs) as a cutting-edge tool for the selective detection and rapid removal of heavy metal ions from water: Recent progress DOI
Mohd Shamim, Hammad Zia, Mohd Zeeshan

et al.

Journal of environmental chemical engineering, Journal Year: 2021, Volume and Issue: 10(1), P. 106991 - 106991

Published: Dec. 16, 2021

Language: Английский

Citations

92
Quick removal of metronidazole from aqueous solutions using metal–organic frameworks DOI

Tina Kalhorizadeh,

Behnaz Dahrazma, Reza Zarghami

et al.

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(19), P. 9440 - 9450

Published: Jan. 1, 2022

Two MOFs were assembled, characterized and investigated in detail as efficient adsorbents for removal of the metronidazole antibiotic. Adsorption isotherms kinetic features also studied.

Language: Английский

Citations

66
Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance DOI Creative Commons
Yangdan Pan,

Soheila Sanati,

Marzieh Nadafan

et al.

Inorganic Chemistry, Journal Year: 2022, Volume and Issue: 61(47), P. 18873 - 18882

Published: Nov. 14, 2022

For the advancement of laser technologies and optical engineering, various types new inorganic organic materials are emerging. Metal-organic frameworks (MOFs) reveal a promising use in nonlinear optics, given presence linkers, metal cluster nodes, possible delocalization π-electron systems. These properties can be further enhanced by inclusion solely such as polyoxometalates prospective low-cost electron-acceptor species. In this study, novel hybrid nanocomposite, namely, SiW12@NU-1000 composed SiW12 (H4SiW12O40) Zr-based MOF (NU-1000), was assembled, completely characterized, thoroughly investigated terms its (NLO) performance. The third-order NLO behavior developed system assessed Z-scan measurements using 532 nm laser. effect two-photon absorption self-focusing significant both NU-1000 SiW12@NU-1000. Experimental studies suggested much superior performance if compared to that NU-1000, which assigned charge-energy transfer between NU-1000. Negligible light scattering, good stability, facile postsynthetic fabrication method promote applicability nanocomposite for optoelectronic purposes. This research may thus open horizons improve enhance MOF-based through compositing metal-organic networks with molecules electron acceptors, paving way generation applications.

Language: Английский

Citations

60
Metal–Organic Framework: An Emergent Catalyst in C–N Cross-Coupling Reactions DOI
Nilankar Diyali, Sagarmani Rasaily, Bhaskar Biswas

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 469, P. 214667 - 214667

Published: July 1, 2022

Language: Английский

Citations

44
Modified magnetic-metal organic framework as a green and efficient adsorbent for removal of heavy metals DOI

Elham Ragheb,

Mojtaba Shamsipur, Fahimeh Jalali

et al.

Journal of environmental chemical engineering, Journal Year: 2022, Volume and Issue: 10(2), P. 107297 - 107297

Published: Feb. 2, 2022

Language: Английский

Citations

43
Two-dimensional metal-organic frameworks: From synthesis to biomedical, environmental, and energy conversion applications DOI
Kayode Adesina Adegoke,

Oyeladun Rhoda Adegoke,

Rasheed A. Adigun

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 473, P. 214817 - 214817

Published: Sept. 26, 2022

Language: Английский

Citations

43
Efficient Removal of Pb(II), Cr(VI), and Tetracycline Hydrochloride from Aqueous Solutions Using UiO-66-AMP@PAN: Thermodynamics, Kinetics, and Isothermal Adsorption DOI
Wenjun Qu, Huili Wang, Guodong Li

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(5), P. 110598 - 110598

Published: July 22, 2023

Language: Английский

Citations

43