Stable CdII-Based Metal–Organic Framework as a Multiresponsive Luminescent Sensor for Acetylacetone, Salicylaldehyde, and Benzaldehyde with High Sensitivity and Selectivity DOI

Rui-Jie Zhang,

Jinjin Wang, Hui Xu

et al.

Crystal Growth & Design, Journal Year: 2023, Volume and Issue: 23(8), P. 5564 - 5570

Published: July 21, 2023

A class of potential luminescent sensing materials has been gradually developed in the form metal–organic frameworks (LMOFs). new LMOF with formula {[Cd(BBZB)(bptc)0.5]·2H2O}n (JXUST-33, BBZB = 4,7-bis(1H-benzimidazole-1-yl)-2,1,3-benzothiadiazole, H4bptc biphenyl-3,3′,5,5′-tetracarboxylic acid) successfully constructed, which exhibits stability structure and effectiveness luminescence. Single-crystal X-ray diffraction studies have shown that two adjacent CdII ions are linked by a bptc4– ligand different directions to plane is further interlaced ligands three-dimensional two-fold interpenetrating framework. JXUST-33 can be used as fluorescent probe identify various organic molecules detect three compounds fluorescence quenching behavior its luminescence properties. In addition, mixed substrate films based on achieve detection acac, SA, BZ via naked eye, great for practical applications.

Language: Английский

Structural Diversity and Tunable Luminescent Properties of Zn(II) Metal–Organic Frameworks with Terephthalate and 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole Linkers DOI
Dmitry I. Pavlov, Alexey A. Ryadun, Vladimir P. Fedin

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 5, 2024

Language: Английский

Citations

7
A robust Eu-MOF as a multi-functional fluorescence sensor for detection of benzaldehyde, Hg2+, and Cr2O72-/CrO42- DOI

Linhan Fan,

Jingyue Zhang, Yun Zhao

et al.

Microchemical Journal, Journal Year: 2023, Volume and Issue: 196, P. 109712 - 109712

Published: Nov. 26, 2023

Language: Английский

Citations

14
A facile and intelligent detection method for diclazuril based on a stable dual emissive Eu3+-dopped metal–organic framework DOI
Yi-Fan Xia, Yanxia Li,

Qing-Yan Xiao

et al.

Food Chemistry, Journal Year: 2024, Volume and Issue: 453, P. 139652 - 139652

Published: May 15, 2024

Language: Английский

Citations

6
Highly Water‐Stable 2D MOF as Dual Sensor for the Ultra‐Sensitive Aqueous Phase Detection of Nitrofuran Antibiotics and Organochlorine Pesticides DOI Creative Commons
Supriya Mondal, Rupam Sahoo, Madhab C. Das

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 20, 2024

Abstract Misuse of antibiotics and pesticides has led to hazardous effects on human health, livestock, agriculture, aquaculture, which urges researchers find simple, rapid, efficient, cost‐effective methods for quick on‐site analysis these organic pollutants with functional materials. Herein, a 2D chemically robust MOF: IITKGP‐71 , {[Cd(MBPz)(2,6‐NDC)]·2H 2 O} n is strategically developed ease in scalability exploited as dual sensors toward the toxic antibiotic pesticide detection via luminescence quenching aqueous medium . The framework displays exceptional chemical robustness water 3 months, an open atmosphere over wide range pH solution (pH = 3–12) day. can selectively quench nitrofuran (NFZ NFT) organochlorine DCN while remaining unaffected by other interfering pesticides, respectively. An excellent trade‐off between high effectivity (high K sv ) sensitivity (low LOD) was achieved targeted analytes. easy scalability, stability, fast responsivity, multi‐responsive nature, recyclability outstanding structural stability made this viable playing crucial role safeguarding aquatic ecosystems public health from pesticides.

Language: Английский

Citations

5
Dualistic Fluorescence as Well as Portable Smartphone-Assisted RGB-Relied Sensing Assay for the Ultra-Sensitive Determination of Pendimethalin in Food and Water Samples by AIEE Active Organic Probes DOI

Pratibha,

Atul Kapoor, Jaspreet Kaur Rajput

et al.

Analytical Chemistry, Journal Year: 2022, Volume and Issue: 94(50), P. 17685 - 17691

Published: Dec. 12, 2022

Herein, a peculiar fluorometric as well smartphone-assisted RGB-relied sensing assay is introduced for determining pendimethalin (PDM) herbicide contents (in parts per trillion level) based on the anthracene-incorporated pyrimidinone/thione probes (S1 to S4). These compounds offered unique and impressive aggregation-induced emission enhancement (AIEE) behavior by aggregation in H2O-dimethylformamide medium. Furthermore, these AIEE active were found display superior selectivity extraordinary sensitivity PDM detection via fluorescence quenching response. The extent of degree was be linearly varied with concentration ranging from 0 20 nM, lower limit 367.8 pM (103.4 ppt) S3 nanoaggregates. detailed investigation revealed that such high designed sensor toward attributable existence dual "photoinduced charge transfer Förster resonance energy process mechanisms". Stern–Volmer plots, Job's plot, Benesi–Hildebrand 1H NMR titrations indicated substantial interactions between PDM. conducted tests provided distinguishable over various other insecticides/pesticides structural nitro analogues. Additionally, presented also applied quantify residues spiked food (vegetables, fruits, grains) water samples. In addition, sensor-coated fluorescent paper test strips fabricated on-site applicability smartphone-relied RGB analysis significantly streamlined operation process, speeds up procedure, novel methodology real-time real

Language: Английский

Citations

22
Highly photo- and triboluminescent lanthanide(iii) coordination polymers based on diphosphine dioxides containing azaheterocyclic linkers DOI
Yuliya A. Bryleva, Vladislav Yu. Komarov, L. A. Glinskaya

et al.

New Journal of Chemistry, Journal Year: 2023, Volume and Issue: 47(21), P. 10446 - 10454

Published: Jan. 1, 2023

Six thermostable one-dimensional Eu 3+ and Tb coordination polymers constructed from diphosphine dioxides bearing azaheterocyclic linkers show bright photo- triboluminescence.

Language: Английский

Citations

13
A novel Co(ii)-based MOF with selective fluorescence as a turn-on sensor for biomarker methylmalonic acid DOI
Rong Luo,

Cungang Xu,

Hai-Jun Yu

et al.

CrystEngComm, Journal Year: 2023, Volume and Issue: 25(29), P. 4120 - 4125

Published: Jan. 1, 2023

A Co( ii )-based MOF exhibits a highly sensitive and selective detection to biomarker methylmalonic acid with low limit favorable recycling performance.

Language: Английский

Citations

13
A highly stable chain-based EuIII metal–organic framework as a turn-on and blue-shift luminescent sensor for dipicolinic acid DOI
Li Wang,

Yu-Lian Zhu,

Teng‐Fei Zheng

et al.

Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(30), P. 10567 - 10573

Published: Jan. 1, 2023

The development of a rapid and selective method for the identification dipicolinic acid (DPA), specific biomarker in Bacillus anthracis spores, is great importance avoidance anthrax infection. Herein, chain-based EuIII metal-organic framework with formula {[Eu3(BTDB)3(μ3-OH)3(H2O)]·solvents}n (JXUST-38, H2BTDB = (benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid) was obtained using 2-fluorobenzoic as pH regulator. JXUST-38 exhibits good chemical thermal stability can specifically recognize DPA N,N-dimethylformamide solution through luminescence enhancement blue-shift effects detection limit 0.05 μM. Furthermore, significant blue shift under UV lamps are obviously observable by naked eye. sensing mechanism attributed to absorbance-induced between DPA. Test paper mixed-matrix membrane based on designed detection. In addition, feasibility biosensing discussed detail.

Language: Английский

Citations

13
Multifunctional Fluorescence Turn-On Sensor for Acetylacetone, Glyoxal, and Salicylaldehyde Based on a Highly Stable 1D → 2D Interlocked Cd(II) Metal–Organic Framework DOI
Xiaoxia Zhang,

Ding-Gui Cai,

Yaping Li

et al.

Crystal Growth & Design, Journal Year: 2023, Volume and Issue: 23(8), P. 5762 - 5769

Published: July 20, 2023

Metal–organic frameworks (MOFs) provide a broad platform for detecting small organic molecules due to their good stabilities and unique luminescent properties. Herein, one-dimensional CdII-based double chain metal–organic framework {[Cd(BBIP)(CDDB)(H2O)]·2H2O}n (JXUST-30) derived from 3,5-bis(1H-benzo[d]imidazol-1-yl)pyridine (BBIP) 4,4′-(9H-carbazole-3,6-diyl)dibenzoic acid (H2CDDB) was successfully synthesized by solvothermal method. Interestingly, the CdII–BBIP could pass through large cavity formed CDDB2– make parallel chains interlocked, resulting in structural transition two-dimensional plane (1D → 2D) enhancement of stability. The intense blue light emission excellent stability aqueous solutions with wide range pH values, solvents, even boiling water JXUST-30 molecules. sensing experiments indicate that can be used as multifunctional fluorescence turn-on sensor acetylacetone (acac), aldehydes (glyoxal salicylaldehyde (SA)) fast response time (<15 s) high sensitivity (detection limits 0.068, 0.060, 0.051 ppm, respectively). In addition, successful preparation devices based on provides possibility practical application detection

Language: Английский

Citations

12
Nanoporous Organic Frameworks as Light-Emitting Diodes: A Review DOI
Elissa O. Shehayeb, Vonika Ka‐Man Au

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(16), P. 18655 - 18675

Published: Jan. 29, 2024

The exponential increase in the use of mobile phones and portable devices has led to a greater demand for cheap lightweight yet efficient light-emitting diodes (LEDs). With significant research interest nanoporous organic frameworks, including metal–organic covalent hydrogen-bonded frameworks (MOFs, COFs, HOFs), their applications electronics, particularly as LEDs, have been growing. This review summarizes main MOFs, HOFs applied LEDs that reported past 10 years. studies are mainly classified depending on types precursors involved, so provide insight into predesignable approach based these can later be commercialized integrated industry technology.

Language: Английский

Citations

4