Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(12), P. 5562 - 5566
Published: Jan. 1, 2024
Two cases of hetero-polyoxotantalates containing {NiTa 10 } are reported for the first time. Ni as a heteroatom is located in center {Ta unit. And 2 exhibits excellent catalytic performance transesterification reactions.
Language: Английский
Rare Metals, Journal Year: 2023, Volume and Issue: 42(11), P. 3638 - 3650
Published: Sept. 29, 2023
Language: Английский
Citations
36
Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(33), P. 13694 - 13708
Published: Jan. 1, 2024
The influence of dopant molecules on the structure and functionality spin-crossover (SCO) materials is surveyed. Two aspects topic are well established. Firstly, isomorphous inert metal ion dopants in SCO lattices a useful probe energetics processes. Secondly, molecular alloys iron(II)/triazole coordination polymers containing mixtures ligands were used to tune their spin-transitions towards room temperature. More recent examples these related discussed that reveal new insights into questions. Complexes which not can also be co-crystallised, either as solid solutions precursor or random distribution homo- hetero-leptic centres alloy. This could powerful method manipulate functionality. Published show different behaviours, may include allosteric switching chemically distinct sites.
Language: Английский
Citations
8
Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 18, 2025
The integration of polyoxometalate (POM) anions with functionalized cations within a single molecule remains challenging task, even though POMs have garnered significant interest over an extended period. Here, we constructed two cobalt(II) complexes by incorporating isomeric POM [Co(pyterpy)2]2+. Intriguingly, locked high-spin (HS) state and spin-crossover (SCO) behavior the 3d7-CoII ion in identical cation [Co(pyterpy)2]2+ were governed α-type β-type [Mo8O26]4- anions, HS-Co(II) showed field-induced slow magnetic relaxation. Furthermore, both exhibited potential as solid-state proton conductors. This study revealed that possessed dual capability modulating magnetism synthesizing multifunctional molecular materials.
Language: Английский
Citations
0
Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(16), P. 6983 - 6992
Published: Jan. 1, 2024
[Fe(bpp)
Language: Английский
Citations
3
European Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 27(8)
Published: Jan. 19, 2024
Abstract Three novel mononuclear 4‐vinylpyridine‐based Fe(III) complexes [FeL(4‐VP)]BPh 4 (4‐VP=4‐vinylpyridine; H 2 L=bis(salicylicdeneaminopropyl)amine, salten, 1 ; L=bis(salicylicdeneaminopropyl)methylamine, salten Me , L=bis(3‐methoxysalicylideneaminopropyl)methylamine, 3‐OMe 3 ) were synthesized and characterized. Single‐crystal X‐ray diffraction analyses revealed that – both present the structure based on 4‐VP coordinated with bis(salicylicdeneaminopropyl)amine its derivatives, which give 2D architectures by various interactions among cations counter‐ions. Magnetic studies showed exhibit one‐step complete spin‐crossover (SCO) behaviours critical transition temperatures ( T 1/2 of 178 87 K respectively, while exhibits incomplete spin crossover behaviour 1/2,3 =93 K). The introduction methyl groups amine nitrogen Schiff base ligands in bigger repulsive effect, further decrease cooperation centres, resulting their occurring at lower temperatures. In addition, presence C−H⋯O weak synergistic led to being higher than .
Language: Английский
Citations
1
Analytical and Bioanalytical Chemistry, Journal Year: 2024, Volume and Issue: 416(27), P. 6137 - 6148
Published: July 24, 2024
Language: Английский
Citations
1
Chemical Communications, Journal Year: 2023, Volume and Issue: 59(29), P. 4312 - 4315
Published: Jan. 1, 2023
An effective method to eliminate grain boundary resistance of crystalline vanadoborate electrolyte was developed. This involved the addition glycerol result in formation many hydrogen bonds between crystal grains, facilitating a rapid transfer protons across boundaries. Using this method, intrinsic conduction fully reflected its bulk materials, valuable for advancing our understanding electrolytes and promoting application these electrolytes.
Language: Английский
Citations
3
Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(9), P. 4063 - 4071
Published: Feb. 16, 2024
Treatment of Co(OTf)2·6H2O, Li[(pzTp)FeIII(CN)3], and H3PMo12O40·nH2O in protic solvents afforded two structurally related Fe–Co cyanometallate complexes: [{(pzTp)Fe(CN)3}3Co3(MeOH)10][PMo12O40]·H2O·11MeOH (1, pzTp– = tetra(pyrazolyl)borate) {[(pzTp)Fe(CN)3]4Co3(MeOH)5(H2O)3}n[HPMo12O40]n·3 nMeOH·6.5nH2O (2). Complex 1 consists a cyanide-bridged hexanuclear [Fe3Co3] cage, characterized by the fused conjunction mutually perpendicular trigonal bipyramids (TBPs, [Fe2Co3] [Co2Fe3]), while complex 2 showcases an intricate tape comprising central chain backbone vertex-sharing TBPs alongside peripheral [Fe2Co2] squares. is among widest one-dimensional coordination assemblies single-crystal X-ray diffraction technique. Magnetic studies revealed that behaved as single magnet with effective energy barrier (Ueff/kB) 46.8 K. Our findings highlight possibilities development cyanometallate-POM hybrid materials captivating magnetic properties.
Language: Английский
Citations
0
Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(12), P. 5562 - 5566
Published: Jan. 1, 2024
Two cases of hetero-polyoxotantalates containing {NiTa 10 } are reported for the first time. Ni as a heteroatom is located in center {Ta unit. And 2 exhibits excellent catalytic performance transesterification reactions.
Language: Английский
Citations
0