Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Metastable
materials
are
considered
promising
electrocatalysts
for
clean
energy
conversions
by
virtue
of
their
structural
flexibility
and
tunable
electronic
properties.
However,
the
exploration
synthesis
metastable
via
traditional
equilibrium
methods
face
challenges
because
requirements
high
precise
control.
In
this
regard,
rapid
method
(RSM),
with
efficiency
ultra-fast
heating/cooling
rates,
enables
production
under
non-equilibrium
conditions.
relationship
between
RSM
properties
remains
largely
unexplored.
review,
we
systematically
examine
unique
benefits
various
techniques
mechanisms
governing
formation
materials.
Based
on
these
insights,
establish
a
framework,
linking
electrocatalytic
performance
Finally,
outline
future
directions
emerging
field
highlight
importance
high-throughput
approaches
autonomous
screening
optimal
electrocatalysts.
This
review
aims
to
provide
an
in-depth
understanding
electrocatalysts,
opening
up
new
avenues
both
fundamental
research
practical
applications
in
electrocatalysis.
Materials,
Journal Year:
2025,
Volume and Issue:
18(5), P. 1184 - 1184
Published: March 6, 2025
Developing
low-cost
electrocatalysts
for
efficient
hydrogen
evolution
in
both
acidic
and
alkaline
conditions
is
crucial
water-electrolytic
applications.
Herein,
MoP
was
synthesized
via
a
simple,
low-cost,
green
phosphorization
route.
More
importantly,
the
Ru/MoP
composite
prepared
using
as-synthesized
as
reactant,
which
exhibited
excellent
catalytic
activity
reaction.
It
showed
lower
overpotentials
of
108
55
mV
at
10
mA·cm−2
solutions,
respectively,
are
superior
to
those
bare
Ru
pristine
well
comparable
or
even
better
than
previously
reported
Ru-
MoP-based
catalysts.
In
addition,
it
also
demonstrated
small
Tafel
slopes
52.6
dec−1
67.9
along
with
long-term
stability.
This
work
provides
an
effective
feasible
route
design
high-efficient
Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Metastable
materials
are
considered
promising
electrocatalysts
for
clean
energy
conversions
by
virtue
of
their
structural
flexibility
and
tunable
electronic
properties.
However,
the
exploration
synthesis
metastable
via
traditional
equilibrium
methods
face
challenges
because
requirements
high
precise
control.
In
this
regard,
rapid
method
(RSM),
with
efficiency
ultra-fast
heating/cooling
rates,
enables
production
under
non-equilibrium
conditions.
relationship
between
RSM
properties
remains
largely
unexplored.
review,
we
systematically
examine
unique
benefits
various
techniques
mechanisms
governing
formation
materials.
Based
on
these
insights,
establish
a
framework,
linking
electrocatalytic
performance
Finally,
outline
future
directions
emerging
field
highlight
importance
high-throughput
approaches
autonomous
screening
optimal
electrocatalysts.
This
review
aims
to
provide
an
in-depth
understanding
electrocatalysts,
opening
up
new
avenues
both
fundamental
research
practical
applications
in
electrocatalysis.
