Cited by A resorcin[4]arene-based MOF as a Lewis acid catalyst for the CO2 coupling reaction

A Porous Carbazolic Al-MOF for Efficient Aerobic Photo-Oxidation of Sulfides into Sulfoxides under Air DOI

Xuezhen Si,

Zuo‐Feng Zhang,

Xiaoying Zhang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(10), P. 4707 - 4715

Published: Feb. 27, 2024

A robust, microporous, and photoactive aluminum-based metal–organic framework (Al-MOF, LCU-600) has been assembled by an in situ-formed [Al3O(CO2)6] trinuclear building unit a tritopic carbazole ligand. LCU-600 shows high water stability permanent porosity for N2 CO2 adsorption. Notably, the incorporation of photoresponsive moieties into makes it highly efficient recyclable photocatalyst aerobic photo-oxidation sulfides sulfoxides under air atmosphere at room temperature. Mechanism investigations unveil that photogenerated holes (h+), superoxide radical anion (O2•–), singlet oxygen (1O2) are critical active spices reaction performed atmosphere.

Language: Английский

Citations

Enhanced catalytic performance for CO2 cycloaddition and Knoevenagel condensation reactions via stable Eu3+ modified Mn-MOF DOI

Meng-Qiang Deng,

Zhen Xu,

Ya‐Yu Zhao

et al.

Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 52, P. 104864 - 104864

Published: July 26, 2024

Language: Английский

Citations

High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione DOI

Wenyu Ding,

Xinyu Tang,

Sheng Chih Jin

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

High-efficiency non-noble cage-based MOFs catalyst for CS 2 waste green disposal through catalytic conversion into high-value thiazolidine-2-thione.

Language: Английский

Citations

Constructing a 3D Zinc Metal-Organic Framework for Ratiometric and Selectively PO43− Sensing and Catalyzing CO2 Chemical Fixation DOI

Gui Xiong,

Qi Li, Lijuan Liang

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1321, P. 139725 - 139725

Published: Aug. 25, 2024

Language: Английский

Citations

Integrating four-, five- and six-coordinated Zn catalytic centers in an ionic-type zinc catalyst for the coupling of CO2 with epoxides DOI

Haizhen Zhang,

Zhen Li, Jia-Jia Wang

et al.

Journal of CO2 Utilization, Journal Year: 2024, Volume and Issue: 82, P. 102760 - 102760

Published: April 1, 2024

Effectively converting greenhouse gas CO2 into value-added chemicals, without the need for cocatalysts or solvents, is a vital objective in order to attain carbon neutrality and promote sustainable development. However, achieving this goal continues pose significant challenges. In study, in-situ formed octadentate N5O3 tripodal ligand (H3L) reacts with ZnBr2 ZnI2 produce two ionic-type zinc catalysts, [Zn2(L)]2[ZnBr4]·4CH3OH (IZ-1) [Zn2(L)]I·CH3OH (IZ-2), respectively. [Zn2(L)] subunit, Zn ions exhibit non-symmetry are coordinated five- six-coordinate mode, Due coexistence of Lewis acidic sites nucleophilic Br- ions, IZ-1 shows remarkable catalytic performance cycloaddition epoxides. Under cocatalyst- solvent-free conditions, it achieves an excellent yield cyclic carbonates, reaching up 99 %. The catalyst can be readily recovered reused at least five times noticeable loss activity. Mechanistic investigation demonstrates that improved activity attributed synergistic effect centers Br-. Moreover, broad substrate scope further highlights its versatility applicability reaction.

Language: Английский

Citations

A resorcin[4]arene-based MOF as a Lewis acid catalyst for the CO2 coupling reaction DOI

Duo Wang,

Xue-Lu Bai,

Jia-Chang Lu

et al.

Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113341 - 113341

Published: Oct. 1, 2024

Language: Английский

Citations