Amplifying Lewis Acidity by Oxidation: Leveraging the Redox-Activity of Bis(3,6-di-tert-butyl-catecholato)silane DOI Creative Commons

Thaddäus Thorwart,

Manuel Schmitt, Lutz Greb

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Oxidation boosts the potential of bis(catecholato)silanes, transforming them into Lewis superacidic radical cations with remarkable catalytic activity in dimerization, hydrodeoxygenation, and carbonyl-olefin metathesis.

Language: Английский

Amplifying Lewis Acidity by Oxidation: Leveraging the Redox-Activity of Bis(3,6-di-tert-butyl-catecholato)silane DOI Creative Commons

Thaddäus Thorwart,

Manuel Schmitt, Lutz Greb

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Oxidation boosts the potential of bis(catecholato)silanes, transforming them into Lewis superacidic radical cations with remarkable catalytic activity in dimerization, hydrodeoxygenation, and carbonyl-olefin metathesis.

Language: Английский

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