Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Synergistic
contributions
of
ternary
alloys
and
TiO
2
-based
supports
accelerate
the
formic
acid
electro-oxidation
process
via
dominant
dehydrogenation
pathway.
Advanced Sustainable Systems,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 5, 2025
Abstract
Designing
electrocatalysts
with
the
selective
C─C
bond
breaking
in
ethanol
electro‐oxidation
is
of
interest
as
an
efficient
strategy
to
accelerate
large‐scale
applications
direct
fuel
cells
(DEFCs).Pt
nanoparticles
(NPs)
are
herein
on
N‐doped
2D
Ti
3
C
2
T
x
MXene
via
two‐step
synthesis
steps
including
NH
‐assisted
hydrothermal
and
NaBH
4
ethylene
glycol
reduction
routes.
With
breaking,
as‐obtained
16
wt.%
Pt/N‐Ti
catalyst
exhibits
435.35
mA
mg
Pt
−1
mass
activity
0.83
cm
−2
specific
activity,
being
1.26‐
1.77‐fold
increase
compared
those
commercially
available
20
Pt/C
(346.21
0.47
).
This
originates
from
advantages
unique
structures
strong
interplay
between
NPs
nitrogen‐doped
.
Also,
shows
superior
CO‐poisoning
resistance
long‐term
stability
for
acidic
reaction
(EOR).
work
demonstrates
potential
heteroatom‐doped
MXenes
1
pathway
selectivity
catalytic
performance
Pt‐based
DEFCs.