A 36-Nucleus Silver-thiolate Cluster Encapsulating Double Sulfates and Co-protected by Cyclen DOI

Wen-Ya Jiang,

Jiaqian Chen,

Zi-Ran Wu

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140423 - 140423

Published: Oct. 1, 2024

Language: Английский

A 36-Nucleus Silver-Thiolate Cluster Encapsulating Double Sulfates and Co-Protected by Cyclen DOI
Kuan‐Guan Liu,

Wen-Ya Jiang,

Jiaqian Chen

et al.

Published: Jan. 1, 2024

New type of cyclic multi-dentate ligand named, Cyclen (1,4,7,10-tetraazacyclododecane, [12]aneN4), was successfully introduced onto the surface a 36-nucleus double sulfates templated silver-thiolate cluster [(SO4)2@Ag36(SPhtBu)24(cyclen)4(CF3CO2)6(OH)2] (1). The nanocluster investigated and characterized by single-crystal X-ray crystallography (SXRD), infrared spectroscopy (IR), photoelectron (XPS), thermogravimetry (TG), ultraviolet−visible (UV) spectroscopy, photoluminescence (PL). shows very good solution stability in four different solvents excellent thermal solid-state. It orange-red emission EtOAc/THF/CH2Cl2/CHCl3 at 77 K. lifetime 1 is over 140 μs, highest quantum yield 25.46 %. temperature-dependent properties solvents, which make them potential candidates fields optical devices for future applications.

Language: Английский

Citations

0
A 36-Nucleus Silver-thiolate Cluster Encapsulating Double Sulfates and Co-protected by Cyclen DOI

Wen-Ya Jiang,

Jiaqian Chen,

Zi-Ran Wu

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140423 - 140423

Published: Oct. 1, 2024

Language: Английский

Citations

0