Multi‐stimuli‐responsive chromic switching self‐assembled with polyoxometalate and copper‐viologen frameworks DOI Creative Commons
Shenzhen Chang,

Hong‐Xiao Zhong,

Yanhong Chen

et al.

cMat., Journal Year: 2024, Volume and Issue: 1(2)

Published: Aug. 19, 2024

Abstract Chromic materials with multi‐stimuli responses have received tremendous attention from industry and academia for their potential applications in smart windows, data storage, military camouflage, molecular switches, modulators, etc. To develop multi‐stimuli‐responsive color‐changing high sensitivity stability, a polyoxometalate‐based copper‐viologen framework, formulated as Cu 2 (H O) (L) [PW 12 O 40 ][OH − ]·2H ( HNU‐97, H L 2+ = 1,1′‐(1,4‐phenylenebis(methylene))bis(4‐carboxypyridinium)), was prepared by mild one‐step self‐assembly strategy. Structural analysis shows that HNU‐97 presents supramolecular structure formed one‐dimensional framework polyoxometalates through rich hydrogen bonds, anion‐π interactions, Discoloration studies show exhibits reversible rapid response characteristics to various external stimuli, such 10 s UV radiation, 5 min heating, ammonium/amine vapors. This mechanism reveals different excitation sources lead preferential transfer directions of electrons, resulting discoloration phenomena. construct stimuli‐chromic good mechanical properties, we successfully introduced into the poly(vinyl alcohol) (PVA)/glycerol (Gly) hydrogel obtain composite HNU‐97@PVA/Gly . Remarkably, combines merits each component can achieve significant behavior under both irradiation ammonia atmosphere. work will provide an idea construction multiple stimuli‐responsive materials.

Language: Английский

Construction of Cobalt-Containing Polyoxovanadate-Based Inorganic–Organic Hybrids as Heterogeneous Catalysts for the Selective Oxidation of Sulfides DOI
Wei Zhang, Xiang Wang, Xinyu Zhao

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 30, 2024

In order to develop efficient catalysts for the selective oxidation of sulfides, in this work, two polyoxovanadate-based inorganic-organic hybrids, [Co(H

Language: Английский

Citations

3
Dimeric four tartaric acid-bridged tetra-Zr-incorporated arsenotungstate showing decent proton conduction DOI
Dong‐Sheng Yang, Lihua Liu, Jiayu Liu

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 16, 2024

Language: Английский

Citations

3
Recent advances in {P 4Mo 6}-based polyoxometalates DOI Creative Commons

Wenrui Deng,

Zihao Zhu,

Yijian Sun

et al.

Polyoxometalates, Journal Year: 2024, Volume and Issue: 3(4), P. 9140071 - 9140071

Published: June 17, 2024

The reduced phosphomolybdate {P4Mo6X31}n- (X = O or OH) ({P4Mo6}) is an important member of polyoxometalates (POMs) with fully Mo atoms, multiple oxygen coordinate sites, excellent optical response and electrochemical properties which have attracted the extensive interests researchers. In past few decades, development {P4Mo6}-based POMs has been relatively slow compared classical most studies mainly focus on synthesis novel structures, some property in fluorescent properties, photocatalytic degradation organic dye electrocatalytic reduction hydrogen peroxide. Recently, received increasing interest due to their unique structure advantages potential applications photocatalysis, electrocatalysis, sensors, proton conduction. This review summarizes process nearly ten years, involving synthesis, diverse fields as well nanocomposites precursors applications. However, there are still challenges such improving scalability intensively studying relationship between structures performances. Future research will explore more energy storage conversion evolution reaction (HER), (OER), battery materials. be helpful for researchers gain a rapid understanding this area value future POMs.

Language: Английский

Citations

2
Assembly of Y(III)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles DOI
Guo‐Ping Yang,

Zhou-Fu Lin,

Xize Zhang

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 35(12), P. 110274 - 110274

Published: July 17, 2024

Language: Английский

Citations

2
Multi‐stimuli‐responsive chromic switching self‐assembled with polyoxometalate and copper‐viologen frameworks DOI Creative Commons
Shenzhen Chang,

Hong‐Xiao Zhong,

Yanhong Chen

et al.

cMat., Journal Year: 2024, Volume and Issue: 1(2)

Published: Aug. 19, 2024

Abstract Chromic materials with multi‐stimuli responses have received tremendous attention from industry and academia for their potential applications in smart windows, data storage, military camouflage, molecular switches, modulators, etc. To develop multi‐stimuli‐responsive color‐changing high sensitivity stability, a polyoxometalate‐based copper‐viologen framework, formulated as Cu 2 (H O) (L) [PW 12 O 40 ][OH − ]·2H ( HNU‐97, H L 2+ = 1,1′‐(1,4‐phenylenebis(methylene))bis(4‐carboxypyridinium)), was prepared by mild one‐step self‐assembly strategy. Structural analysis shows that HNU‐97 presents supramolecular structure formed one‐dimensional framework polyoxometalates through rich hydrogen bonds, anion‐π interactions, Discoloration studies show exhibits reversible rapid response characteristics to various external stimuli, such 10 s UV radiation, 5 min heating, ammonium/amine vapors. This mechanism reveals different excitation sources lead preferential transfer directions of electrons, resulting discoloration phenomena. construct stimuli‐chromic good mechanical properties, we successfully introduced into the poly(vinyl alcohol) (PVA)/glycerol (Gly) hydrogel obtain composite HNU‐97@PVA/Gly . Remarkably, combines merits each component can achieve significant behavior under both irradiation ammonia atmosphere. work will provide an idea construction multiple stimuli‐responsive materials.

Language: Английский

Citations

2