Reconstruction of Ni-based catalyst for electrocatalytic urea oxidation reaction
Xuena Gao,
No information about this author
Jianguo Dong,
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Huimin Yang
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et al.
Journal of Alloys and Compounds,
Journal Year:
2025,
Volume and Issue:
1012, P. 178477 - 178477
Published: Jan. 1, 2025
Language: Английский
Sustainable Synthesis, Surface Characterization, and electrocatalytic performance of Novel Ni-Fe Selenide as an Efficient Electrode Material for oxidation of Urea in Aqueous Solutions
Surfaces and Interfaces,
Journal Year:
2025,
Volume and Issue:
unknown, P. 105790 - 105790
Published: Jan. 1, 2025
Language: Английский
Strategies for Modulating Ni-based Layered Double Hydroxides for Boosting Urea Electrooxidation
Chang‐Hyeon Ji,
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Jipeng Wang,
No information about this author
Sheng Feng
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et al.
Journal of Alloys and Compounds,
Journal Year:
2025,
Volume and Issue:
unknown, P. 179306 - 179306
Published: Feb. 1, 2025
Language: Английский
Layered‐Hierarchical Dual‐Lattice Strain Suppresses NixSe Surface Reconstruction for Stable OER in Alkaline Fresh/Seawater Splitting
Meilian Tu,
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Zhixiao Zhu,
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Yanxiang He
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et al.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 13, 2025
Abstract
Transition
metal
selenides
(TMSe)
are
promising
oxygen
evolution
reaction
(OER)
electrocatalysts
but
act
as
precursors
rather
than
the
actual
active
phase,
transforming
into
amorphous
oxyhydroxides
during
OER.
This
transformation,
along
with
formation
of
selenium
oxyanions
and
unstable
heterointerfaces,
complicates
structure‐activity
relationship
reduces
stability.
work
introduces
novel
“layered‐hierarchical
dual
lattice
strain
engineering”
to
inhibit
surface
reconstruction
Ni
x
Se
by
modulating
both
nickel
foam
(NF)
substrate
Mo
2
N
nanosheets
(NM)
nanorods‐nanosheets
catalytic
layer
(NiSe‐Ni
0.85
Se‐NiO,
NSN)
ultrafast
interfacial
bimetallic
NiFeOOH
coating,
achieving
optimized
NM/NSN/NiFeOOH
configuration.
The
NM
induces
strain,
enhancing
OER
activity
improving
electron
transport
adhesion,
while
coating
additional
mitigating
oxidative
degradation,
reinforcing
structural
integrity.
catalyst
demonstrates
exceptional
performance
low
overpotentials
208
mV@10
mA
cm
−2
outstanding
stability
over
100
h
at
in
alkaline
freshwater
seawater.
Theoretical
analysis
shows
that
effectively
prevents
degradation
preserving
sites
for
optimal
intermediate
interactions
stabilizing
electronic
environment.
provides
a
strategy
TMSe
beyond.
Language: Английский
Hierarchical Superhydrophilic/Superaerophobic Ni3S2/VS2 Nanorod-Based Bifunctional Electrocatalyst Supported on Nickel Foam for Overall Urea Electrolysis
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 25, 2024
The
design
and
preparation
of
effective
nonprecious
metal-based
catalysts
for
the
urea
oxidation
reaction
(UOR)
coupled
with
hydrogen
evolution
(HER)
are
great
significance
to
solve
both
energy
shortage
environmental
pollution
problems.
In
this
study,
a
novel
hierarchical
superhydrophilic
superaerophobicity
three-dimensional
nanorod-like
bifunctional
catalyst
heterostructure
(Ni
Language: Английский