Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(10), P. 2721 - 2729
Published: Oct. 1, 2024
Language: Английский
Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(10), P. 2721 - 2729
Published: Oct. 1, 2024
Language: Английский
Crystal Growth & Design, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 5, 2025
MOF-based heterojunctions can significantly enhance the efficiency of photocatalytic hydrogen production; however, construction efficient remains a formidable challenge. In this study, we successfully developed series Type II by growing TiO2 on Cr-based MOF, thereby regulating generation, separation, and transportation photogenerated charge carriers to improve evolution performance. Among these, 23%TiO2/MIL-101(Cr) photocatalyst exhibited highest production activity, achieving 884.01 μmol g–1 in just 5 h, which is 6.8 6.0 times that pure MIL-101(Cr) TiO2, respectively. Additionally, demonstrated excellent cyclic stability. Tiny particles were proven mainly deposited surface N2 sorption isotherm analyses, transmission electron microscopy (TEM), high-resolution TEM, high-angle annular dark field scanning microscopy, etc. Characterization techniques such as situ XPS confirmed formation TiO2/MIL-101(Cr) heterostructure. Band structure analysis indicates meets thermodynamic requirements for production. Furthermore, transient photocurrent measurements, electrochemical impedance analysis, photoluminescence reveal possesses superior capabilities carrier transport, resulting from kinetic perspective. This research offers valuable insights into preparation development photocatalysts
Language: Английский
Citations
2Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 100466 - 100466
Published: Nov. 1, 2024
Language: Английский
Citations
10Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 28, 2025
The directed regulation of proton transport pathways in conductors, facilitated by the well-defined crystal structures metal–organic frameworks (MOFs), is important for development advanced materials. In this study, MOF-808-2.5SO4-His synthesized progressive modification on framework using functional molecules. incorporation sulfate and imidazole groups into results a high conductivity 1.37 × 10–2 S cm–1 at 70 °C 98% relative humidity (RH). analysis temperature-dependent indicates that facilitates through Grotthuss mechanism RH temperature range 30–70 °C. Additionally, exhibits good cycling stability durability performance. This feasible approach enhances comprehension transfer promotes viable strategies controllable construction conductors.
Language: Английский
Citations
1Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115396 - 115396
Published: Jan. 1, 2025
Language: Английский
Citations
0Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 22, 2025
Language: Английский
Citations
0Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 136296 - 136296
Published: Jan. 1, 2025
Language: Английский
Citations
0Science for energy and environment., Journal Year: 2025, Volume and Issue: unknown, P. 1 - 1
Published: Jan. 6, 2025
Review An Overview of Light-Assisted CO2 Cycloaddition for Cyclic Carbonate: Paths Photo-Induced Thermal-Catalysis, Photocatalysis and Photo-Thermal Synergistic Catalysis Bin Zhu 1, Qichao Cao Xin Ding 1,*, Xiaolong Yang 1,2,* 1 School Chemistry Chemical Engineering, Qingdao University, 308 NingXia Road, 266071, China 2 State Key Laboratory Bio-Fibers Eco-Textiles, Collaborative Innovation Center Shandong Marine Bio-Based Fibers Ecological Textiles, * Correspondence: [email protected] (X.D.); [email protected] (X.Y.) Received: 4 November 2024; Revised: 6 January Accepted: 22 2025; Published: February 2026 Abstract: The increase concentration significantly results in severe greenhouse effect. Reducing emission chemically utilizing are effective means to solve this problem. cycloaddition reaction with epoxide is atomically economical environmentally friendly. However, current catalytic systems still have a long way go high efficiency under mild conditions. Solar energy has demonstrated excellent characteristics direct photothermal utilization, photocatalytic reactions, photoelectrochemical reactions recently. Therefore, herein review summarizes the research work on solar mediated past decade. Firstly, heat generated by effects confined local space can be more effectively absorbed molecules efficient greatly reducing consumption traditional thermal reactions. carbon-based materials, polyoxometalates (POM), metal organic frameworks (MOFs), covalent (COFs), ionic liquids (ILs) as catalysts reviewed analyzed; Secondly, semiconductor exhibit activity due activation reactants photogenerated charges holes. Single atom catalysts, composites, atomic clusters, MOFs, COFs, Porous polymers (POPs), others used such Finally, light synergistic catalysis system external heating synergy introduced analyzed. Last but not least, some issues development analyzed discussed, future prospects proposed basis.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125174 - 125174
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123614 - 123614
Published: March 1, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180321 - 180321
Published: April 1, 2025
Language: Английский
Citations
0