Rational Design of Photofunctional Ionic Manganese(II) Bromide Materials Through Isomer Engineering for High-Performance X-Ray Imaging
Xinghao Sheng,
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Xiao-Kang Zheng,
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Tao Peng
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et al.
Journal of Inorganic and Organometallic Polymers and Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 4, 2025
Language: Английский
Lead-Free Scintillator Based on a Luminescent Green-Emitting Material Derived from Manganese(II) Chloride for High-Resolution X-Ray Imaging
Journal of Inorganic and Organometallic Polymers and Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 2, 2025
Abstract
Manganese(II)
halides
have
attracted
significant
research
attention
because
of
their
unique
zero-dimensional
structures,
low
toxicity,
structural
diversity,
and
tunable
photoluminescent
properties.
However,
the
development
neutral
manganese(II)
chlorides
has
lagged
behind
bromide
counterparts
in
X-ray
imaging
applications.
Herein,
we
report
a
green-emitting
monodentate
chloride
complex
(
H-Cl
)
by
introducing
cyclohexyldiphenylphosphine
oxide
as
ligand,
which
could
be
synthesized
via
simple
room-temperature
solvent
evaporation
method.
Complex
exhibits
bright
photoluminescence
with
an
emission
peak
at
516
nm
full-width
half-maximum
(FWHM)
61
nm,
achieves
quantum
yield
(PLQY)
16.69%,
surpassing
most
reported
chlorides.
As
scintillator,
realizes
detection
limit
1.581
µGy/s,
is
much
lower
than
that
standard
for
medical
diagnostics.
It
also
shows
high
spatial
resolution
exceeding
9.6
lp/mm,
highlighting
its
potential
advanced
scintillator
design
high-resolution
technology.
Graphical
Language: Английский
Flexible 3D printed fibers of novel manganese halides with superior acid/alkali resistance for X-ray imaging and radiation warning
Yunluo Wang,
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Tianrui Zhou,
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Jie Chen
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et al.
Chemical Engineering Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 163495 - 163495
Published: May 1, 2025
Language: Английский
Template Synthesis of Iodocuprate and Iodoargentate with Photocatalytic Activity and Second Harmonic Generation Efficiency
Mengyuan Xie,
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Tong Liu,
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Yanzhi Xia
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et al.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 20, 2024
In
virtue
of
the
cationic
tri(pyridin-4-yl)amine
(TPA)
derivatives
acting
as
templates,
two
iodometallates,
[Me
Language: Английский
Eco-friendly and facile one-step synthesis of manganese perovskite (TMPEA)2MnBr4 for high performance X-ray imaging
Yinke Liu,
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Chen Zhao,
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Dan Liŭ
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et al.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(52), P. 38539 - 38546
Published: Jan. 1, 2024
Inorganic-organic
metal
halogen
perovskites,
especially
eco-friendly
have
been
intensively
developed
for
X-ray
imaging
due
to
the
high
sensitivity,
low
detection
limit,
and
light
yield.
In
this
work,
we
successfully
synthesized
perovskite
trimethylphenylammonium
manganese(ii)
bromide
((TMPEA)
Language: Английский