Guest-Molecule-Induced Glass-Crystal Transition in Organic–Inorganic Hybrid Antimony Halides DOI

Xuexia Lu,

Yang‐Peng Lin, Zhen Liu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 18, 2025

The glassy state of inorganic-organic hybrid metal halides combines their excellent optoelectronic properties with the outstanding processability glass, showcasing unique application potential in solar devices, display technologies, and plastic electronics. Herein, by tailoring organic cation from N-phenylpiperazine to dimethylamine gradually, four types zero-dimensional antimony are obtained various optical thermal properties. guest water molecules crystal (N-phenylpiperazine)2SbCl6·Cl·5H2O lead largest distortion Sb-halogen unit, resulting red emission different yellow other compounds. More importantly, molecule-induced hydrogen-bond network would prolong relaxation time into an equilibrium state, formation state. This is previous strategy adopting large cations for glass transition. Through rheological studies, we shape initial understanding underlying kinetics halide glass. work provides a simpler more convenient approach developing superior processing performance.

Language: Английский

Guest-Molecule-Induced Glass-Crystal Transition in Organic–Inorganic Hybrid Antimony Halides DOI

Xuexia Lu,

Yang‐Peng Lin, Zhen Liu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 18, 2025

The glassy state of inorganic-organic hybrid metal halides combines their excellent optoelectronic properties with the outstanding processability glass, showcasing unique application potential in solar devices, display technologies, and plastic electronics. Herein, by tailoring organic cation from N-phenylpiperazine to dimethylamine gradually, four types zero-dimensional antimony are obtained various optical thermal properties. guest water molecules crystal (N-phenylpiperazine)2SbCl6·Cl·5H2O lead largest distortion Sb-halogen unit, resulting red emission different yellow other compounds. More importantly, molecule-induced hydrogen-bond network would prolong relaxation time into an equilibrium state, formation state. This is previous strategy adopting large cations for glass transition. Through rheological studies, we shape initial understanding underlying kinetics halide glass. work provides a simpler more convenient approach developing superior processing performance.

Language: Английский

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