Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142703 - 142703
Published: May 1, 2025
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142703 - 142703
Published: May 1, 2025
Language: Английский
ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
The molecular design of new compounds with enhanced third-order nonlinear optical (NLO) applications is an important research topic in the area functional materials. present study describes a 3D metal-organic framework [Zn3(μ3-bta)2(μ4-ata)2]n (abbreviated as NH2-Zn-MUM-6), generated solvothermally from multicomponent system composed zinc(II) ions and 2-aminoterephthalic acid (H2ata) 1H-benzotriazole (Hbta) linkers. Apart intricate porous structure seh-4,6-Imma topology, this MOF features good thermal stability exceptional NLO characteristics. These were investigated detail by Z-scan method, revealing remarkably high values refractive index (n2 = 30.83 × 10-8 cm2/W) absorption coefficient (β 4.06 10-4 cm/W). An extended π-conjugation both aromatic ligands, μ3-bta- μ4-ata2-, their interaction Zn centers contribute to formation highly polarizable system, thus significantly enhancing its capacity for behavior. This broadens family materials provides insights into relationship between properties amino-functionalized mixed-linker MOFs viewpoint such all-optical switching data transmission.
Language: Английский
Citations
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0Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142703 - 142703
Published: May 1, 2025
Language: Английский
Citations
0