In Situ Coordination-Catalyzed o-Vanillin Underwent a One-Pot Tandem Reaction to Construct Complex Chiral Tetrameric Isomer-Based Hexanuclear Clusters DOI
Ran Li,

Ju-Fen Ai,

Jiayi Tao

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

In this work, Dy(NO3)3·6H2O and o-vanillin reacted under "one-pot" conditions, achieving for the first time four efficient condensations of obtaining a pair chiral hexanuclear clusters R/S-Dy6. The Dy(III) ions in structure R/S-Dy6 are arranged planar quadrilateral with ion derived from each upper lower ends, forming shape similar to "chair". complex ligands H4LR1 H4LS1 were obtained simple through multistep tandem reaction. Their formation process involved series reaction steps, including free radical coupling form pinacol an situ o-vanillin. Magnetic studies show that have magnetic anisotropy and/or low excited states. addition, has outstanding ability produce reactive oxygen species low-power light irradiation shows excellent photodynamic sterilization. inhibition zones against Escherichia coli about 2.09 2.99 cm, Staphylococcus aureus 2.51 2.93 respectively. This work not only provides vivid example synthesis organic products but also promotes progress lanthanide clusters' crystal engineering.

Language: Английский

Distinct off–on fluorescence signal from dual-response lanthanide metal–organic frameworks for ratiometric sensing of anthrax biomarker DOI
Rong Wu, Nan Wang,

Rusi Hao

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2025, Volume and Issue: unknown, P. 126196 - 126196

Published: April 1, 2025

Language: Английский

Citations

0
In Situ Coordination-Catalyzed o-Vanillin Underwent a One-Pot Tandem Reaction to Construct Complex Chiral Tetrameric Isomer-Based Hexanuclear Clusters DOI
Ran Li,

Ju-Fen Ai,

Jiayi Tao

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

In this work, Dy(NO3)3·6H2O and o-vanillin reacted under "one-pot" conditions, achieving for the first time four efficient condensations of obtaining a pair chiral hexanuclear clusters R/S-Dy6. The Dy(III) ions in structure R/S-Dy6 are arranged planar quadrilateral with ion derived from each upper lower ends, forming shape similar to "chair". complex ligands H4LR1 H4LS1 were obtained simple through multistep tandem reaction. Their formation process involved series reaction steps, including free radical coupling form pinacol an situ o-vanillin. Magnetic studies show that have magnetic anisotropy and/or low excited states. addition, has outstanding ability produce reactive oxygen species low-power light irradiation shows excellent photodynamic sterilization. inhibition zones against Escherichia coli about 2.09 2.99 cm, Staphylococcus aureus 2.51 2.93 respectively. This work not only provides vivid example synthesis organic products but also promotes progress lanthanide clusters' crystal engineering.

Language: Английский

Citations

0