SSRN Electronic Journal,
Journal Year:
2022,
Volume and Issue:
unknown
Published: Jan. 1, 2022
The
coupling
reaction
allows
simple
structural
fragments
to
be
constructed
and
sequentially
assembled
by
C-X
bond
synthesize
a
variety
of
active
molecular
frameworks.
Different
from
the
traditional
single-metal
catalyst,
synergistic
effect
bimetal
provides
special
catalytic
activity
that
cannot
obtained
thus
emerging
as
an
efficient
alternative
mode.
In
this
paper,
we
used
Cu-Al
bimetallic
heterogeneous
mesoporous
materials
participate
in
sequential
assembly
C-S
C-N
bonds,
which
effectively
catalyzed
synthesis
2-substituted
benzothiazole
heterocyclic
systems.
addition,
GW610
with
antitumor
was
synthesized
easily
efficiently
strategy.
Journal of Chemical Research,
Journal Year:
2020,
Volume and Issue:
45(3-4), P. 237 - 241
Published: Nov. 24, 2020
We
describe
a
practical
protocol
for
efficiently
preparing
diaryl
sulfide
compounds
using
Cu–OMS-2
as
the
catalyst.
originates
from
manganese
oxide
octahedral
molecular
sieves
modified
with
copper
ions
and
catalyzes
C–S
coupling
reaction
of
substituted
thiophenols
aryl
halides.
This
has
advantages
environmental
friendliness,
simple
operation,
high
yields,
good
tolerance
functional
groups,
catalytic
material
can
be
recycled
several
times.
SSRN Electronic Journal,
Journal Year:
2022,
Volume and Issue:
unknown
Published: Jan. 1, 2022
The
coupling
reaction
allows
simple
structural
fragments
to
be
constructed
and
sequentially
assembled
by
C-X
bond
synthesize
a
variety
of
active
molecular
frameworks.
Different
from
the
traditional
single-metal
catalyst,
synergistic
effect
bimetal
provides
special
catalytic
activity
that
cannot
obtained
thus
emerging
as
an
efficient
alternative
mode.
In
this
paper,
we
used
Cu-Al
bimetallic
heterogeneous
mesoporous
materials
participate
in
sequential
assembly
C-S
C-N
bonds,
which
effectively
catalyzed
synthesis
2-substituted
benzothiazole
heterocyclic
systems.
addition,
GW610
with
antitumor
was
synthesized
easily
efficiently
strategy.