Synthesis of 1,4-oxathiins via [3+3] annulation of pyridinium 1,4-zwitterionic thiolates with iodonium ylides DOI Creative Commons

Zhibin Niu,

Chao Pi, Yangjie Wu

et al.

Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

A straightforward and valuable approach for the synthesis of 1,4-oxathiins has been developed via [3 ​+ ​3] annulation pyridinium 1,4-zwitterionic thiolates with iodonium ylides. C–S C–O bonds were formed in one pot manner this transformation, which features readily available substrates, excellent tolerance functional groups mild reaction conditions. It would be great value construction biological pharmacological activity.

Language: Английский

Photochemical Decarboxylative Radical Alkylation/Cyclization Reaction to Fused Nitrogen Heterocycles by LiI/PPh3 Catalysis DOI

Jia‐Li Sui,

Xin‐Qian Liu,

Shun‐Dan Li

et al.

Chinese Journal of Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 10, 2024

Comprehensive Summary A visible‐light‐induced decarboxylative radical cascade cyclization reaction between N ‐(2‐cyanoaryl)‐acrylamides and alkyl ‐(acyloxy)phthalimide (NHPI esters) for the construction of phenanthridine derivatives has been developed. This approach utilizes lithium iodide (LiI) triphenylphosphine (PPh 3 ) as redox catalysts is produced through photoactivation electron donor‐acceptor (EDA) complex. series primary, secondary, tertiary alkyl‐substituted phenanthridines are prepared in up to 82% yield without transition‐metal catalysts, chemical oxidants, or metal‐/organic dye‐based photocatalysts.

Language: Английский

Citations

1
Synthesis of 1,4-Oxathiins Via [3+3] Annulation of Pyridinium 1,4‐Zwitterionic Thiolates with Iodonium Ylides DOI

Zhibin Niu,

Chao Pi, Yangjie Wu

et al.

Published: Jan. 1, 2024

A straightforward and valuable approach for the synthesis of 1,4-oxathiins has been developed via [3+3] annulation pyridinium 1,4-zwitterionic thiolates with iodonium ylides. C-S C-O bonds were formed in one pot manner this transformation, which features readily available substrates, excellent tolerance functional groups mild reaction conditions. It would be great value construction biological pharmacological activities.

Language: Английский

Citations

0
Synthesis of 1,4-oxathiins via [3+3] annulation of pyridinium 1,4-zwitterionic thiolates with iodonium ylides DOI Creative Commons

Zhibin Niu,

Chao Pi, Yangjie Wu

et al.

Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

A straightforward and valuable approach for the synthesis of 1,4-oxathiins has been developed via [3 ​+ ​3] annulation pyridinium 1,4-zwitterionic thiolates with iodonium ylides. C–S C–O bonds were formed in one pot manner this transformation, which features readily available substrates, excellent tolerance functional groups mild reaction conditions. It would be great value construction biological pharmacological activity.

Language: Английский

Citations

0