Synthesis of 1,4-epoxy-2-aryltetrahydro-1-benzazepines via rhodium(iii)-catalyzed C–H allylation/intramolecular 1,3-dipolar cycloaddition DOI
Xuan Wang, Jianlong Li,

Haifang Du

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(17), P. 2401 - 2404

Published: Jan. 1, 2024

Herein, we report a new synthetic route to 1,4-epoxy-2-aryltetrahydro-1-benzazepine derivatives with high efficiency, namely the Rh(III)-catalyzed C-H allylation of nitrones allyl precursors, followed by subsequent intramolecular 1,3-dipolar cycloaddition, deliver title compounds. This reaction is regio- and stereo-selective, generating

Language: Английский

Synthesis of 1,4-epoxy-2-aryltetrahydro-1-benzazepines via rhodium(iii)-catalyzed C–H allylation/intramolecular 1,3-dipolar cycloaddition DOI
Xuan Wang, Jianlong Li,

Haifang Du

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(17), P. 2401 - 2404

Published: Jan. 1, 2024

Herein, we report a new synthetic route to 1,4-epoxy-2-aryltetrahydro-1-benzazepine derivatives with high efficiency, namely the Rh(III)-catalyzed C-H allylation of nitrones allyl precursors, followed by subsequent intramolecular 1,3-dipolar cycloaddition, deliver title compounds. This reaction is regio- and stereo-selective, generating

Language: Английский

Citations

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