TBHP‐Mediated Hydroxyperfluoroalkylation of Alkenes with Perfluoroalkyl Iodides to Construct β‐Perfluoroalkyl Alcohols DOI
Jiantao Zhang, Weiming Zhu,

Renhua Su

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(17), P. 3572 - 3577

Published: April 10, 2024

Abstract A three‐component strategy for the synthesis of β‐perfluoroalkyl allyl alcohols from 1,3‐dienes is developed. diverse range synthetically valuable are obtained in moderate to high yields. Broad substrate scope and good functional group tolerance observed. This method also applicable mono‐olefins 1,3‐enynes. The control experiment results demonstrate that hydroxyl OH product comes TBHP. In addition, practicality mild reaction conditions make these synthetic transformations attractive organic synthesis.

Language: Английский

TBHP‐Mediated Hydroxyperfluoroalkylation of Alkenes with Perfluoroalkyl Iodides to Construct β‐Perfluoroalkyl Alcohols DOI
Jiantao Zhang, Weiming Zhu,

Renhua Su

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(17), P. 3572 - 3577

Published: April 10, 2024

Abstract A three‐component strategy for the synthesis of β‐perfluoroalkyl allyl alcohols from 1,3‐dienes is developed. diverse range synthetically valuable are obtained in moderate to high yields. Broad substrate scope and good functional group tolerance observed. This method also applicable mono‐olefins 1,3‐enynes. The control experiment results demonstrate that hydroxyl OH product comes TBHP. In addition, practicality mild reaction conditions make these synthetic transformations attractive organic synthesis.

Language: Английский

Citations

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