Skeletal Reorganization Emanated via the Course of Heterocyclic N1–N2 Bond Cleavage: Electrosynthetic Approach DOI
Saiful Islam, Dwaipayan Das,

Rahul Dev Mandal

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(21), P. 15686 - 15693

Published: Oct. 21, 2024

A unified method toward the synthesis of functionalized diazepines and quinazolines through reorganization molecular skeleton has been devised. The process is indulged by electrical energy via a domino N1–N2 bond cleavage followed concomitant ring closing, initiating from cinnolines indazoles as designed precursors. Additionally, an intermolecular homologation also established to synthesize densely dihydroquinazolines 2,3-diaryl-indazoles acetonitrile involving same electrochemical strategy.

Language: Английский

Skeletal Reorganization Emanated via the Course of Heterocyclic N1–N2 Bond Cleavage: Electrosynthetic Approach DOI
Saiful Islam, Dwaipayan Das,

Rahul Dev Mandal

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(21), P. 15686 - 15693

Published: Oct. 21, 2024

A unified method toward the synthesis of functionalized diazepines and quinazolines through reorganization molecular skeleton has been devised. The process is indulged by electrical energy via a domino N1–N2 bond cleavage followed concomitant ring closing, initiating from cinnolines indazoles as designed precursors. Additionally, an intermolecular homologation also established to synthesize densely dihydroquinazolines 2,3-diaryl-indazoles acetonitrile involving same electrochemical strategy.

Language: Английский

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