One-pot synthesis of 2,2′-biquinolines from aromatic amines using oxygen as an oxidant under metal-free conditions DOI
Yunfeng Liao,

Hualan Gao,

Hongrui Qi

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 14, 2024

We have developed an efficient method for the synthesis of unsymmetrical and symmetrical 2,2′-biquinolines under 55% HI-catalyzed conditions using oxygen as oxidant cheap readily available aromatic amines feedstocks in one pot.

Language: Английский

Visible-Light-Induced C(sp3)-H Activation for Minisci Alkylation of Pyrimidines Using CHCl3 as Radical Source and Oxidant DOI

Jiatian Zhuo,

Jinshan Liu, Min Zhou

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

A highly efficient Minisci reaction of pyrimidines with alkyl radical generated from visible-light-induced activation simple C(sp3)-H feedstocks such as (cyclo)alkanes, ethers, alcohols, esters, and amides is reported. mechanistic study revealed that was via hydrogen atom transfer (HAT) dichloromethyl (·CHCl2), which by photoreduction chloroform.

Language: Английский

Citations

0
One-pot synthesis of 2,2′-biquinolines from aromatic amines using oxygen as an oxidant under metal-free conditions DOI
Yunfeng Liao,

Hualan Gao,

Hongrui Qi

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 14, 2024

We have developed an efficient method for the synthesis of unsymmetrical and symmetrical 2,2′-biquinolines under 55% HI-catalyzed conditions using oxygen as oxidant cheap readily available aromatic amines feedstocks in one pot.

Language: Английский

Citations

0