Nickel-Catalyzed C(sp3)–C(sp3) Cross-Coupling of Carboxamides and Unactivated Alkyl Iodides DOI

Haochen Li,

Guohua Ren, Xi Chen

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 22, 2025

The construction of C(sp3)-C(sp3) bonds through cross-coupling reactions unactivated alkyl halides and C-radical precursors presents a significant challenge in organic synthesis. Herein, we report strategy for the formation using as alkylation reagents via 1,5-hydrogen atom transfer (HAT) process. proceed under mild conditions, demonstrating remarkable tolerance diverse array functional groups. This method possesses potential to expand new pathways

Language: Английский

Visible-light-induced synthesis of bibenzofuranones via a cerium-mediated energy transfer process DOI

J. F. Lv,

Yatao Lang,

Chao‐Jun Li

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Synthesis of bibenzofuranones from benzils via a radical cyclization-dimerization tandem process, efficiently constructing C–O/C–C bonds and contiguous quaternary carbon centers in single step, was reported.

Language: Английский

Citations

0
Nickel-Catalyzed C(sp3)–C(sp3) Cross-Coupling of Carboxamides and Unactivated Alkyl Iodides DOI

Haochen Li,

Guohua Ren, Xi Chen

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 22, 2025

The construction of C(sp3)-C(sp3) bonds through cross-coupling reactions unactivated alkyl halides and C-radical precursors presents a significant challenge in organic synthesis. Herein, we report strategy for the formation using as alkylation reagents via 1,5-hydrogen atom transfer (HAT) process. proceed under mild conditions, demonstrating remarkable tolerance diverse array functional groups. This method possesses potential to expand new pathways

Language: Английский

Citations

0