Antiaromaticity in molecular assemblies and materials DOI Creative Commons
Roy Lavendomme, Masahiro Yamashina

Chemical Science, Journal Year: 2024, Volume and Issue: 15(45), P. 18677 - 18697

Published: Jan. 1, 2024

Antiaromatic rings are infamously unstable and difficult to work with but they possess unusual electronic properties that make them interesting for fundamental applied research. This perspective presents reports on discrete or polymeric assemblies made from antiaromatic building blocks, bound by either covalent linkages supramolecular interactions. Compared materials, more commonly studied, most efforts have been devoted their preparation property studies, whereas applications scarcely suggested. Future research in the field should focus developing benefit specific of rings. On other hand, few antiaromatic-based materials hint at a promising future this class organic electronics. To guide non-experts, different compounds evaluated suitability as blocks larger assemblies.

Language: Английский

Antiaromaticity in molecular assemblies and materials DOI Creative Commons
Roy Lavendomme, Masahiro Yamashina

Chemical Science, Journal Year: 2024, Volume and Issue: 15(45), P. 18677 - 18697

Published: Jan. 1, 2024

Antiaromatic rings are infamously unstable and difficult to work with but they possess unusual electronic properties that make them interesting for fundamental applied research. This perspective presents reports on discrete or polymeric assemblies made from antiaromatic building blocks, bound by either covalent linkages supramolecular interactions. Compared materials, more commonly studied, most efforts have been devoted their preparation property studies, whereas applications scarcely suggested. Future research in the field should focus developing benefit specific of rings. On other hand, few antiaromatic-based materials hint at a promising future this class organic electronics. To guide non-experts, different compounds evaluated suitability as blocks larger assemblies.

Language: Английский

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