Photoredox/NHC cooperative catalysis for alkylacylation of styrenes: An alternative method for the synthesis of γ-aminoketones
Ke-Yang Yu,
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Fu Cheng,
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Dong-Sen Duan
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et al.
Tetrahedron Letters,
Journal Year:
2025,
Volume and Issue:
156, P. 155450 - 155450
Published: Jan. 8, 2025
Language: Английский
Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration
Ming Hou,
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Yuanrui Wang,
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Hefei Yang
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et al.
ChemistryEurope,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Abstract
Carbon
monoxide,
as
a
crucial
C1
synthon,
has
been
widely
used
in
the
difunctionalization
of
alkenes.
Additionally,
nitrogen‐centered
radicals
(NCRs)
are
also
effective
intermediates
for
constructing
C−N
bonds.
Herein,
radical‐mediated
aminative
carbonylation
strategy
producing
β
‐amino
ketones
from
tertiary
allyl
alcohols
disclosed.
Good
yields
with
different
functional
groups
were
generated
effectively
under
light
irradiation.
Language: Английский