Visible-Light-Mediated Synthesis of Anomeric S-Aryl Glycosides via Electron Donor–Acceptor Complex Using Thianthrenium Salts DOI Creative Commons

Zhuoyi Zhou,

Yufeng Zhang, Zhiqiang Yu

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(6), P. 1315 - 1315

Published: March 14, 2025

S-Aryl glycosides are not only popular glycosyl donors in carbohydrate chemistry but also serve as valuable tools various biological studies, which has brought significant attention to their preparation. However, there remains a pressing need for greener synthesis methods this area. In response, mild, sustainable, and metal- photocatalyst-free electron donor–acceptor (EDA)-mediated approach synthesizing using 1-thiosugar aryl thianthrenium salt was developed. Our strategy utilizes the donor, overcoming traditional reliance on electron-rich thiols, such or carbonyl typically required forming EDA complexes.

Language: Английский

Visible-Light-Mediated Synthesis of Anomeric S-Aryl Glycosides via Electron Donor–Acceptor Complex Using Thianthrenium Salts DOI Creative Commons

Zhuoyi Zhou,

Yufeng Zhang, Zhiqiang Yu

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(6), P. 1315 - 1315

Published: March 14, 2025

S-Aryl glycosides are not only popular glycosyl donors in carbohydrate chemistry but also serve as valuable tools various biological studies, which has brought significant attention to their preparation. However, there remains a pressing need for greener synthesis methods this area. In response, mild, sustainable, and metal- photocatalyst-free electron donor–acceptor (EDA)-mediated approach synthesizing using 1-thiosugar aryl thianthrenium salt was developed. Our strategy utilizes the donor, overcoming traditional reliance on electron-rich thiols, such or carbonyl typically required forming EDA complexes.

Language: Английский

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