Unlocking the Reactivity of the C-In Bond: Alkyl Indium Reagents as a Source of Radicals Under Photocatalytic Conditions DOI Creative Commons
Anton A. Gladkov, Vitalij V. Levin,

Demian Y. Cheboksarov

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Generation of organic radicals from organometallic compounds is a key step in metallaphotoredox cross-coupling reactions. The ability organoindium to serve as sources alkyl under light promoted oxidative conditions described. Organoindium reagents were used dual photocatalytic/nickel with aryl bromides. These can be conveniently obtained primary, secondary and tertiary bromides chlorides using novel indium(i) bromide/lithium bromide system. Both steps, the formation organoindiums their are insensitive towards air moisture tolerate wide variety functional groups.

Language: Английский

Unlocking the Reactivity of the C-In Bond: Alkyl Indium Reagents as a Source of Radicals Under Photocatalytic Conditions DOI Creative Commons
Anton A. Gladkov, Vitalij V. Levin,

Demian Y. Cheboksarov

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Generation of organic radicals from organometallic compounds is a key step in metallaphotoredox cross-coupling reactions. The ability organoindium to serve as sources alkyl under light promoted oxidative conditions described. Organoindium reagents were used dual photocatalytic/nickel with aryl bromides. These can be conveniently obtained primary, secondary and tertiary bromides chlorides using novel indium(i) bromide/lithium bromide system. Both steps, the formation organoindiums their are insensitive towards air moisture tolerate wide variety functional groups.

Language: Английский

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