Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones DOI
Yuqin Wang,

Yiling Zeng,

Ya-Nan Tian

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 13, 2024

Rh( iii )-catalyzed C–H activation and annulation of N -aryl cyclic hydrazides with vinyl acetate to build cinnolines cinnolin-4(1 H )-ones have been reported.

Language: Английский

Divergent [5 + 1] Annulation of o-Aminobenzamides with Vinylene Carbonate as a Multifunctional Reagent DOI
Jiang Nan, Hanqing Zhang, Lanxin Zhu

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

A divergent [5 + 1] cyclization reaction of o-aminobenzamides with vinylene carbonate has been developed, rapidly generating three types cyclic molecules including quinazolinones, 2-methylquinazolinones, and 2,3-dihydroquinazolinones high chemoselectivity. In this discovery, blooms as a multifunctional reagent to participate in cyclization. The potential new finding is further emphasized by assembling the benzothiazole heteroarene via [4 version tolerating bioactive units well.

Language: Английский

Citations

0
Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones DOI
Yuqin Wang,

Yiling Zeng,

Ya-Nan Tian

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 13, 2024

Rh( iii )-catalyzed C–H activation and annulation of N -aryl cyclic hydrazides with vinyl acetate to build cinnolines cinnolin-4(1 H )-ones have been reported.

Language: Английский

Citations

0