CCl4-Induced Synthesis of Phosphonothioates, Sulfoxides, and Sulfones from Sodium Sulfinates DOI

Xiangyun Yang,

Silong Chen,

Nan Huang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 22, 2025

An external reductant-free and acid-free synthesis of phosphonothioates from odorless sodium sulfinates induced by CCl4 (1.0 equiv) under mild conditions has been achieved. This transformation provides an efficient synthetic approach to in up 98% yield with good functional group compatibility. In addition, unexpected CCl4-induced sulfoxides sulfones using DMSO as the solvent developed.

Language: Английский

CCl4-Induced Synthesis of Phosphonothioates, Sulfoxides, and Sulfones from Sodium Sulfinates DOI

Xiangyun Yang,

Silong Chen,

Nan Huang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 22, 2025

An external reductant-free and acid-free synthesis of phosphonothioates from odorless sodium sulfinates induced by CCl4 (1.0 equiv) under mild conditions has been achieved. This transformation provides an efficient synthetic approach to in up 98% yield with good functional group compatibility. In addition, unexpected CCl4-induced sulfoxides sulfones using DMSO as the solvent developed.

Language: Английский

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