Energy-Transfer-Enabled Truce–Smiles Rearrangement Using Sulfonamides as Sulfonyl Radical Precursors DOI

Fuyang Yue,

Ming‐Xing Li, Jiayi Li

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: May 19, 2025

We have developed a method for visible-light-induced radical Smiles-Truce rearrangement reactions that use sulfonamide-derived imines as sulfonyl precursors. This enables efficient functionalization of alkenes and has the advantages having wide substrate scope not emitting sulfur dioxide, thereby constituting an environmentally friendly approach synthesis structurally complex sulfones, alcohols, amines.

Language: Английский

Energy-Transfer-Enabled Truce–Smiles Rearrangement Using Sulfonamides as Sulfonyl Radical Precursors DOI

Fuyang Yue,

Ming‐Xing Li, Jiayi Li

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: May 19, 2025

We have developed a method for visible-light-induced radical Smiles-Truce rearrangement reactions that use sulfonamide-derived imines as sulfonyl precursors. This enables efficient functionalization of alkenes and has the advantages having wide substrate scope not emitting sulfur dioxide, thereby constituting an environmentally friendly approach synthesis structurally complex sulfones, alcohols, amines.

Language: Английский

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