Progress in heterocyclic chemistry, Journal Year: 2021, Volume and Issue: unknown, P. 119 - 173
Published: Jan. 1, 2021
Language: Английский
Environmental Chemistry Letters, Journal Year: 2021, Volume and Issue: 19(4), P. 3315 - 3358
Published: April 12, 2021
Language: Английский
Citations
81
Inorganic Chemistry Frontiers, Journal Year: 2020, Volume and Issue: 8(2), P. 499 - 545
Published: Nov. 16, 2020
In this review, we highlighted Pd nanocatalysts which have been used in the development of sustainable organic transformations including transfer hydrogenation, C–H bond activation, and some carbon–carbon couplings last five years.
Language: Английский
Citations
40
Catalysts, Journal Year: 2021, Volume and Issue: 11(11), P. 1266 - 1266
Published: Oct. 21, 2021
Over the past few decades, use of transition metal nanoparticles (NPs) in catalysis has attracted much attention and their C–C bond forming reactions constitutes one most important applications. A huge variety NPs, which have showed high catalytic activity for reactions, been developed up to now. Many kinds stabilizers, such as inorganic materials, magnetically recoverable porous organic–inorganic composites, carbon polymers, surfactants utilized develop NPs catalysts. This review classified outlined categories by type support.
Language: Английский
Citations
27
Organic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(23), P. 6505 - 6512
Published: Jan. 1, 2022
A palladium catalyzed stereo-convergent aminocarbonylation of 1,3-dienes with nitroarenes has been developed. The reaction mixtrues E / Z isomers reacted and produced ( , )-dienamides high stereoselectivities.
Language: Английский
Citations
15
The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(3), P. 1568 - 1577
Published: Jan. 17, 2023
A palladium-catalyzed cyclization coupling of iodoarene-tethered alkynes with cyclobutanone-derived N-tosylhydrazones is reported, providing a convenient and efficient approach to benzofuran-3-cyclobutylidenes. On this basis, spirocyclobutanes can be generated smoothly in an cascade manner by the addition dienophiles. Good yields scalability are demonstrated. Sequential intramolecular carbopalladation, palladium-carbene migratory insertion, δ-hydride elimination, cycloaddition processes involved.
Language: Английский
Citations
9
The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(3), P. 1613 - 1624
Published: Jan. 16, 2023
A novel strategy to access unsymmetrically linked heterocycles via palladium-catalyzed acylcycloimidoylation of alkyne-tethered carbamoyl chlorides with isocyanides has been developed. Functionalized were successfully applied as imine-containing heterocycle precursors capture the vinyl-PdII intermediate, which was generated from a syn-carbopalladation alkyne, followed by subsequent intramolecular C-H bond activation/imidoylative Heck reactions. Methylene oxindoles within Z-tetrasubstituted olefins obtained in high yields excellent stereoselectivities. Broad functional groups well tolerated under mild reaction conditions.
Language: Английский
Citations
8
The Journal of Organic Chemistry, Journal Year: 2020, Volume and Issue: 85(16), P. 10514 - 10524
Published: Aug. 5, 2020
The binaphthyl stabilized palladium nanoparticles (Pd-BNP) catalyzed single-step, stereoselective domino synthesis of symmetrically and unsymmetrically all-carbon tetrasubstituted olefin containing oxindoles from readily accessible anilides has been developed. Pd-BNP catalyst showed a wide range functional group tolerance that enabled building library heteroaromatics. This reusable Pd reflected its utility in the biologically important AMP-activated protein kinase deprived any metal contamination. nanocatalyst was easily recovered reused five times without appreciable loss particle size or catalytic activity.
Language: Английский
Citations
15
Nanomaterials, Journal Year: 2021, Volume and Issue: 11(8), P. 1891 - 1891
Published: July 23, 2021
Metal nanoparticles have been deeply studied in the last few decades due to their attractive physical and chemical properties, finding a wide range of applications several fields. Among them, well-defined nano-structures can combine main advantages heterogeneous homogeneous catalysts. Especially, catalyzed multi-step processes for production added-value chemicals represent straightforward synthetic methodologies, including tandem sequential reactions that avoid purification intermediate compounds. In particular, palladium- copper-based nanocatalysts are often applied, becoming current strategy sustainable synthesis fine chemicals. The rational tailoring nanosized materials involving both those immobilized on solid supports liquid phases organic herein reviewed.
Language: Английский
Citations
14
Organic Chemistry Frontiers, Journal Year: 2021, Volume and Issue: 9(2), P. 305 - 310
Published: Nov. 23, 2021
A dual nickel-/palladium-catalyzed gem -difluorovinylation of alkynyl bromoarenes is presented. This method proceeds smoothly to afford various dihydrobenzofuran compounds containing gem-difluorovinyl fragments with excellent stereoselectivities.
Language: Английский
Citations
13
Advanced Synthesis & Catalysis, Journal Year: 2020, Volume and Issue: 363(8), P. 2117 - 2123
Published: Dec. 15, 2020
Abstract An cascade intramolecular 5‐ exo‐dig cyclization of N ‐(2‐iodophenyl)propiolamides and sequential amination/etherification (with ‐hydroxybenzamides, phenyl hydroxycarbamate) protocol for the synthesis amino‐ phenoxy‐substituted 3‐methyleneindolinones using unexpensive Pd(PPh 3 ) 4 as catalyst has been developed. The enables assembly structurally important oxindole cores featuring moderate functional group tolerance (particularly halo group), affording a broad spectrum products with diverse substituents in good to excellent yields. magnified image
Language: Английский
Citations
12