MXenes: Versatile 2D materials with tailored surface chemistry and diverse applications

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 90, P. 253 - 293

Published: Dec. 5, 2023

Language: Английский

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Scope, evaluation and current perspectives of MXene synthesis strategies for state of the art applications

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(13), P. 7351 - 7395

Published: Jan. 1, 2024

This review provides insights into MXene synthesis methods, mechanisms, terminations, modifications strategies and important applications. Additionally, the advantages, drawbacks, suggestions, precautions have been discussed.

Language: Английский

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Delamination of Chlorine-Terminated MXene Produced Using Molten Salt Etching

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(4), P. 1998 - 2006

Published: Feb. 6, 2024

MXenes produced by Lewis acid molten salt (LAMS) etching of MAX phases have attracted the community's attention due to their controllable surface chemistry. However, delamination is challenging hydrophobicity multilayer MXene and strong interactions between halogen-terminated sheets. The current method involves dangerous chemicals such as n-butyllithium or sodium hydride, making scale-up difficult limiting practical application this class MXenes. In work, we present a simple efficient for from LAMS synthesis while maintaining LiCl anhydrous polar organic solvents are used delamination. Films delaminated flexible an electrical conductivity 8000 S/cm, which maintained after week exposure 95% humidity. This successful delamination, preservation inherent properties, stability under high-humidity conditions dramatically expand range chemistries available research potential applications.

Language: Английский

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Solid lubrication performance of hybrid Ti3C2T /MoS2 coatings

Carbon, Journal Year: 2024, Volume and Issue: 225, P. 119067 - 119067

Published: March 27, 2024

Language: Английский

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Emerging trends in MXene research: Synthesis, process and hybrid with nanomaterials for biosensing

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 531, P. 216493 - 216493

Published: Feb. 8, 2025

Language: Английский

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Recent progress in the antidegradation strategies of two-dimensional transition metal carbides (MXenes)

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112762 - 112762

Published: April 10, 2024

Language: Английский

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Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(37)

Published: June 21, 2024

Surface chemistry of MXenes is great interest as the terminations can define intrinsic properties this family materials. The diverse and tunable also distinguish from many other 2D Conventional fluoride-containing reagents etching approaches resulted in with mixed fluoro-, oxo-, hydroxyl surface groups. relatively strong chemical bonding MXenes' metal atoms oxygen fluorine makes post-synthetic covalent modifications such unfavorable. In minireview, we focus on recent advances uniform terminations. Unconventional methods, including Lewis acidic molten salt (LAMS) bottom-up direct synthesis, have been proven successful producing halide-terminated MXenes. These synthetic strategies opened new possibilities for because weaker bonds facilitate modifications. Both computational experimental results termination-dependent are summarized discussed. Finally, offer our perspective opportunities challenges exciting research field.

Language: Английский

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Comprehensive analysis of MAX phase and MXene materials for advanced photocatalysis, electrocatalysis and adsorption in hydrogen evolution and storage

Journal of Industrial and Engineering Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

Over the past twenty-five years, MAX phases and their derivatives, MXenes, have become a focal point in materials research. These compounds seamlessly blend ceramic metallic properties, offering high thermal electrical conductivity, mechanical strength, low density, resistance to extreme conditions. Their versatility positions them as promising candidates for diverse applications, particularly advanced photo-catalysis electro-catalysis hydrogen evolution. Furthermore, MXenes are potential storage materials, with unique structures that provide ample space efficient gas release, vital clean energy technologies like fuel cells. This review aims comprehensively analyze roles photo-catalysis, electro-catalysis, storage, focus on layered crystal structure. integrate superior metal attributes, while offer tunable electronic enhance catalytic performance. Continued exploration is crucial unlock full potential, advancing beyond.

Language: Английский

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MXenes and its composite structures: synthesis, properties, applications, 3D/4D printing, and artificial intelligence; machine learning integration

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101433 - 101433

Published: Jan. 1, 2025

Language: Английский

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MXenes and MXene‐based Metal Hydrides for Solid‐State Hydrogen Storage: A Review

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(16)

Published: June 17, 2024

Hydrogen-driven energy is fascinating among the everlasting sources, particularly for stationary and onboard transportation applications. Efficient hydrogen storage presents a key challenge to accomplishing sustainability goals of economy. In this regard, solid-state in nanomaterials, either physically or chemically adsorbed, has been considered safe path establishing goals. Though metal hydrides have extensively explored, they fail comply with set targets practical utilization. Recently, MXenes, both bare form hybrid state hydrides, proven their flair ascertaining hydrides' theoretical experimental capabilities far beyond fancy materials current state-of-the-art technologies. This review encompasses significant accomplishments achieved by MXenes (primarily 2019-2024) enhancing performance various hydride such as MgH

Language: Английский

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