NH2-MIL-125 MOF integrated translucent mesoporous polymer monolith as dual-light responsive new-generation photocatalyst for the expeditious decontamination of perennial pharmaceuticals

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(5), P. 110355 - 110355

Published: June 16, 2023

Language: Английский

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Emerging metal-organic framework-based photocatalysts for solar-driven fuel production

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 524, P. 216292 - 216292

Published: Nov. 11, 2024

Language: Английский

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ZnIn₂S₄ Heterojunctions Constructed with In-MOF Precursor for Photocatalytic Hydrogen Evolution without Cocatalysts

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(14), P. 6546 - 6554

Published: March 27, 2024

Znln2S4 has great prospects for photocatalytic water splitting to hydrogen by visible light. Herein, a novel Znln2S4–In-MOF (ZnInMS4) photocatalyst is elaborately synthesized in situ method with In-MOF as the template and In3+ source. ZnInMS4 overcomes fast interface charge recombination sluggish lifetime via formed heterojunctions. Photoelectrochemical measurements reveal that charge-transfer kinetics enhanced since introduced act reliable charge-transport channel. exhibits outstanding cocatalyst-free H2 evolution rate of 70 μmol h–1 under irradiation (λ > 420 nm), which 3.2-fold higher than Znln2S4. In addition, shows good stability 16 h continuous reaction. This work illustrates feasibility MOF precursor instead inorganic salts directly synthesize photocatalysts high performance.

Language: Английский

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A Visible Light-Driven α-MnO₂/UiO-66-NH₂ S-Scheme Photocatalyst toward Ameliorated Oxy-TCH Degradation and H₂ Evolution

Langmuir, Journal Year: 2024, Volume and Issue: 40(8), P. 4514 - 4530

Published: Feb. 13, 2024

Photocatalytic hydrogen production and pollutant degradation using a heterogeneous photocatalyst remains an alternative route for mitigating the impending pollution energy crisis. Hence, development of cost-effective environmentally friendly semiconducting materials with high solar light captivation nature is imperative. To overcome this challenge, α-MnO2 nanorod (NR)-modified MOF UiO-66-NH2 (UNH) was prepared via facile solvothermal method, which efficient toward H2 evolution oxy-tetracycline hydrochloride (O-TCH) degradation. The field-emission scanning electron microscopy (FESEM) high-resolution transmission (HR-TEM) results α-MnO2@UNH (MnU) hybrid reveals its embedded in matrix, X-ray photoelectron spectroscopy (XPS) result confirms interaction UNH moiety NRs. Additionally, outstanding separation photogenerated excitons charge-transfer efficacy are further validated by photoluminescence (PL), time-resolved (TRPL), electrochemical impedance (EIS), transient photocurrent analysis, key causes photoactivity augmentation MnU composites. MnU-2 composite shows superior O-TCH efficiency 93.23% excellent rate about 410.6 μmol h–1 upon irradiation. This study provides significant evidence favor suggested mediator-free S-scheme-adapted charge migration path, it effectively explains enhanced exciton leading to extraordinary catalytic proposed composite.

Language: Английский

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Ag/Pd bimetallic nanoparticle-loaded Zr-MOF: an efficacious visible-light-responsive photocatalyst for H₂O₂ and H₂ production

Energy Advances, Journal Year: 2024, Volume and Issue: 3(5), P. 1073 - 1086

Published: Jan. 1, 2024

A noble bimetallic nanoparticle-modified UiO-66-NH 2 MOF (Ag/Pd@UiO-66-NH ) composite photocatalyst for efficient hydrogen peroxide and production.

Language: Английский

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