CrystEngComm,
Journal Year:
2024,
Volume and Issue:
26(39), P. 5489 - 5517
Published: Jan. 1, 2024
The
state
of
the
art
developments
and
application
MOFs
as
suitable
catalysts
for
capturing
converting
CO
2
into
valuable
chemical
products
are
critically
reviewed
in
this
perspective.
Chemical Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Different
operando
characterization
techniques
for
the
time-dependent
screening
of
SACs
under
working
conditions
and
electrochemical
CO
2
RR
applications
SAC-derived
materials
have
been
reviewed.
Chemistry - An Asian Journal,
Journal Year:
2024,
Volume and Issue:
19(22)
Published: Aug. 1, 2024
Highly
efficient
photocatalysts
can
be
fabricated
using
favorable
charge
transfer
nanocomposite
channel
structures.
This
study
adopted
pulsed
laser
ablation
in
liquid
(PLAL)
to
obtain
rGO-bridged
TiO
ChemCatChem,
Journal Year:
2024,
Volume and Issue:
16(22)
Published: Aug. 10, 2024
Abstract
CO
2
reduction
by
sunlight
under
mild
reaction
conditions
is
a
research
area
of
increasing
interest
expected
to
favor
decarbonization
and
produce
fuels
chemicals
in
the
circular
economy.
We
hereby
report
on
development
series
titanium
oxide‐based
solids
produced
calcination
MIL‐125(Ti)‐NH
decorated
with
RuO
x
nanoparticles
(1
wt
%)
material
at
temperatures
from
350
650
°C
used
as
photocatalysts
for
methanation
simulated
irradiation
(45
mW/cm
)
<200
1.5
atm
total
pressure.
The
synthesized
highest
photoactivity
(4.73
mmol
g
−1
CH
4
22
h
an
apparent
quantum
yield
400,
500
750
nm
0.76,
0.65
0.54
%,
respectively),
comparing
favorably
activities
other
MOF‐based
materials
reported
so
far.
Insights
into
material's
photocatalytic
performance
study
possible
pathways
during
were
obtained
electrochemical
impedance,
electron
spin
resonance,
photoluminescence
situ
FT‐IR
spectroscopies
together
transient
photocurrent
hydrogen
temperature
programed
desorption
measurements.
showed
possibility
using
precursors
develop
metal
oxide
enhanced
solar‐driven
gaseous
photomethanation.
Metals,
Journal Year:
2024,
Volume and Issue:
14(8), P. 922 - 922
Published: Aug. 14, 2024
Hydrogen
(H2)
is
considered
to
be
the
best
carbon-free
energy
carrier
that
can
replace
fossil
fuels
because
of
its
high
density
and
advantages
not
producing
greenhouse
gases
air
pollutants.
As
a
green
sustainable
method
for
hydrogen
production,
electrochemical
evolution
reaction
(HER)
has
received
widespread
attention.
Currently,
it
great
challenge
prepare
economically
stable
electrocatalysts
HER
using
non-precious
metals.
In
this
study,
Co/Co3O4/Ti3C2Tx
catalyst
was
synthesized
by
supporting
Co/Co3O4
with
Ti3C2Tx.
The
results
show
excellent
activity
durability
in
1
mol
L−1
KOH,
overpotential
Tafel
slope
at
10
mA·cm−2
were
87
mV
61.90
dec−1,
respectively.
stability
explained
as
follows:
Ti3C2Tx
provides
skeleton
large
number
attachment
sites
Co/Co3O4,
thus
exposing
more
active
sites;
unique
two-dimensional
structure
an
efficient
conductive
network
rapid
electron
transfer
between
electrolyte
during
electrocatalysis;
Co3O4
makes
hydrophilic,
which
accelerate
release
rate
bubbles;
adsorption
deionization
H2O
synthesize
H2.
This
study
new
approach
design
preparation
low-cost
high-performance
catalysts.