Frontier Electrolytes for Efficient Sodium-Ion Batteries DOI Creative Commons
Xinyu Zhang

Highlights in Science Engineering and Technology, Journal Year: 2024, Volume and Issue: 121, P. 22 - 30

Published: Dec. 24, 2024

The considerable demand for renewable energy sources and the mounting concern about environmental pollution has created a new development opportunity in field of secondary batteries, which can store chemical place electrical energy. In 2010s, attention was drawn to sodium batteries. A sodium-ion battery (SIB) is specific kind that be recharged, given plentiful element on Earth more stable than lithium Consequently, there been growing body research activity this field. This article will describe electrolytes SIBs, significantly contribute electrochemical safety characteristics SIBs. discussed include liquid electrolyte, solid solid-liquid composite electrolyte. most common use an organic solvent comprises salt (NaPF6 or NaClO4) carbonate. electrolyte successfully matched with range anodes cathodes, resulting satisfactory overall performance. Nevertheless, obvious drawback corroding metal electrodes over extended periods potential concerns.

Language: Английский

Zinc selenide/cobalt selenide in nitrogen-doped carbon frameworks as anode materials for high-performance sodium-ion hybrid capacitors DOI
Lin Gao, Minglei Cao, Chuankun Zhang

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(5)

Published: Sept. 18, 2024

Language: Английский

Citations

76
Recent progress on covalent organic frameworks and their composites as electrode materials for supercapacitors DOI
Ruidong Li, Jie Li, Qianwen Liu

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 8(1)

Published: Dec. 26, 2024

Language: Английский

Citations

22
Functional biomass/biological macromolecular phase change composites and their applications in different scenarios: A review DOI Creative Commons
Yang Cao, Jingtao Su,

Yongshuang Xiao

et al.

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 141377 - 141377

Published: Feb. 1, 2025

Language: Английский

Citations

6
In situ synthesis of three-dimensional core–shell structure Bi2WO6/BiOCl and photocatalytic degradation of trinitrotoluene wastewater DOI Creative Commons

Xiyang Zhou,

Sitong Zhang, Wenhui Liu

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2025, Volume and Issue: 8(1)

Published: Jan. 2, 2025

Abstract Bi 2 WO 6 /BiOCl nanocomposites with three-dimensional core–shell structure were synthesized by a two-step hydrothermal method. The compounds characterized XRD, SEM, TEM, HR-TEM, EDX, SAED, XPS, PL, UV–Vis DRS, photoelectrochemical, and photodegradation experiments. result showed that the catalytic activity of was significantly better than BiOCl. effect amount on properties composite studied. had highest photocatalytic degradation efficiency for TNT, rate reached 90% after 180 min visible light irradiation. In process reaction 4.5 is highest, which 0.20057 −1 . After 4 cycles, TNT remained at 80%. free radical trapping experiments holes superoxide anions played major role in wastewater /BiOCl. Based results experiment, Mott-Schottky test, ultraviolet–visible diffuse reflection spectroscopy, mechanism enhancing proposed.

Language: Английский

Citations

1
Zinc-ion batteries at elevated temperatures: linking material design to wearable/biocompatible applications DOI Creative Commons
Yutong Wu,

Qiong He,

Yunlei Zhou

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2025, Volume and Issue: 8(1)

Published: Jan. 17, 2025

Language: Английский

Citations

1
Effects of Sodium Sources on Nonaqueous Precipitation Synthesis of β″-Al2O3 and Formation Mechanism of Uniform Ionic Channels DOI

Xiaolong Huang,

Guo Feng,

Jun Mu

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

High-temperature and long-term sintering of β″-Al2O3 solid electrolyte (Beta″ Alumina Solid Electrolyte, BASE) can easily cause Na2O volatilization. It reduces the (SE) quality, resulting in low ion conductivity electrolyte. is also difficult to form uniform ionic channels. This work designs a simple nonaqueous precipitation through de-etherification heterogeneous polymerization reaction between optimal sodium source ethoxide aluminum isopropoxide synthesize highly active precursor powders with Na-O-Al as skeleton, effectively reducing synthesis temperatures minimizing Importantly, residual organic groups temperature 1150 °C promote formation situ carbon uniformly. In-situ mass fraction about 3.98% will uniformly distributed transport channels diameter 1-3 μm when at 1580 °C. These ensure migration rate ions 0.028 S/cm 300

Language: Английский

Citations

1
Advances in Aerosol Nanostructuring: Functions and Control of Next-Generation Particles DOI
Eka Lutfi Septiani, Takashi Ogi

Langmuir, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 15, 2024

Nanostructured particles (NSPs), with their remarkable properties at the nanoscale, possess key functions required for unlocking a sustainable future. Fabricating these using aerosol methods and spraying processes enables precise control over particle morphology, structure, composition, crystallinity during in-flight transformation. In this Perspective, significant impact of NSPs on technological advancement energy environmental applications is discussed. Furthermore, incorporating in situ/operando assessment techniques alongside machine deep learning explored. Finally, future development trends perspective advancing synthesis via process are elaborated further driving innovations supersmart carbon-neutral society.

Language: Английский

Citations

5
Frontiers of MXenes-based hybrid materials for energy storage and conversion applications DOI Creative Commons

Md. Yasir Bhat,

Waheed A. Adeosun,

Kaitlyn Prenger

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 8(1)

Published: Dec. 17, 2024

Since their breakthrough in 2011, MXenes, transition metal carbides, and/or nitrides have been studied extensively. This large family of two-dimensional materials has shown enormous potential as electrode for different applications including catalysis, energy storage, and conversion. MXenes are suitable the aforementioned due to high electrical conductivity, tunable surface chemistry, area, layered structure, flexural property, hydrophilicity amongst others. article aims cover development MXene/hybrid structures computational insight, synthesis techniques, structural morphology, properties, conversion storage devices. Several approaches adopted develop MXene hybrids, such modifying traditional by decorating surfaces, intercalating, in-situ fabrication, target electrochemical performance. In addition, this review concisely uniquely presented recent advances application hybrid battery design, clean hydrogen fuel generation, carbon dioxide reduction, other relevant reactions. Finally, latest trends prospects also summarized.

Language: Английский

Citations

4
Inorganic Solid‐State Electrolytes for Solid‐State Sodium Batteries: Electrolyte Design and Interfacial Challenges DOI Creative Commons
Dongsoo Lee, Ashok Kumar Kakarla, Seho Sun

et al.

ChemElectroChem, Journal Year: 2025, Volume and Issue: 12(3)

Published: Jan. 6, 2025

Abstract Recent advancements in inorganic solid electrolytes (ISEs), achieving sodium (Na)‐ion conductivities exceeding 10 ‐2 S cm ‐1 at room temperature (RT), have generated significant interest the development of solid‐state batteries (SSSBs). However, ISEs face challenges such as their limited electrochemical stability windows (ESWs) and compatibility issues with high‐capacity, high‐voltage cathode materials Na metal anodes. The success high‐performance SSSBs hinges on developing ideal that deliver high + ion conductivities, robust chemical stability, well constructed electrode/ISE interfaces. This review explores fundamental principles strategies to optimize SSSB performance by addressing related interfaces, emphasizing many interfacial are intrinsically linked ISE properties. It highlights recent research, including mechanisms Na‐ion conduction key factors influencing it, crystal structure, lattice dynamics, point defects, grain boundaries. also discusses prototyping for cell design from perspectives material defect chemistry. Additionally, identifies future opportunities advancing provides rational solutions guide research toward practical realization SSSBs. Keywords: Solid‐state batteries; Inorganic electrolytes; Interfacial mechanism; Electrochemical window; Ionic conductivity; Modification

Language: Английский

Citations

0
A Zwitterion Coupled All‐Solid‐State Single Ion Conducting Polymer Electrolyte via Photoinitiated Thiol‐Ene Click Polymerization DOI Open Access

Kun-Yuan Tu,

Jinnan Zhang, Guang–Nan Luo

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

The all-solid-state single ion conducting polymer electrolyte has a bottleneck in ionic conductivity even though it can prevent concentration polarization. Here, lithium 3,3'-(diallylammonio)bis(propane-1-sulfonyl(trifluoromethyl sulfonyl)imide) (LiDAA(PSI)2) with symmetrical "one positive, two negative" structure and unsaturated double bonds for propagation, is synthesized. LiDAA(PSI)2 copolymerized 1,2-ethanedithiol poly(ethylene glycol) diacrylate via photoinitiated thiol-ene click polymerization forms random copolymer, SPZ short. For comparison, 3-(diallylamino)propane-1-sulfonyl(trifluoromethyl (LiDAAPSI) corresponding copolymer SP are 7Li resonance peak position of shifts to low-field compared that LiDAAPSI, indicating weaker electrostatic attraction. responsible the shift, taking effect charge conjugation. Unsurprisingly, 1.69e-5 S cm-1 at 60 °C, which 1.9 times SP. Lithium electroplating stripping 0.0125 mA [email protected] mAh cm-2 °C performed. An metal secondary battery demonstrated. Zwitterion coupled possesses structure, conjugation weaken interaction, inspires design synthesis electrolytes zwitterion effect.

Language: Английский

Citations

0