Mechanism and Kinetics for Copper Leaching by Complexing with Lysine Bearing Two Amino Groups
Mengying Li,
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Qingliang Wang,
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Weijie Guo
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et al.
Langmuir,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 15, 2025
In
order
to
overcome
the
environmental
problems
associated
with
ammonia
volatilization
during
leaching
process,
effects
of
copper
by
amino
acids
various
numbers
and
substitution
positions
functional
groups
were
systematically
studied.
The
results
showed
that
lysine
had
best
efficiency
for
copper.
When
concentration
was
0.2
mol/L,
temperature
20
°C,
molar
ratio
3.88,
stirring
speed
250
rpm,
pH
10,
time
14
h,
rate
reached
99%.
containing
smelting
slag
has
an
excellent
effect
on
selective
kinetic
indicated
rate-limiting
step
process
is
controlled
interfacial
chemical
reaction,
apparent
activation
energy
64.8
kJ/mol.
Fourier
transform
infrared
spectroscopy
(FT-IR)
X-ray
photoelectron
(XPS)
analyses
confirmed
COO-
-NH
in
can
form
complexes
ions.
Compared
conventional
methods,
this
approach
not
only
achieves
environmentally
benign
disposal
heavy
metal
pollutants
but
also
provides
a
novel
strategy
green
recovery
valuable
metals
from
secondary
resources.
Language: Английский
Investigating the selective extraction of metals from nickel sulfide tailings using salt roasting and acid leaching
Minerals Engineering,
Journal Year:
2025,
Volume and Issue:
231, P. 109433 - 109433
Published: May 22, 2025
Language: Английский
Recovery of Lesser-Known Strategic Metals: The Gallium and Germanium Cases
Processes,
Journal Year:
2024,
Volume and Issue:
12(11), P. 2545 - 2545
Published: Nov. 14, 2024
Being
not
as
popular
other
elements,
such
cobalt,
lithium,
and
rare
earth
both
gallium
germanium
have
wide
use
in
target
developments/industries,
thus
making
them
valuable
strategically
critical
metals.
The
principal
sources
for
the
recovery
of
metals
are
secondary
wastes
bauxite
(gallium)
or
zinc
(germanium)
industries;
also,
their
recycling
from
waste
materials
is
necessary.
characteristics
these
make
hydrometallurgical
operations
widely
useful
recovering
various
containing
them.
present
work
reviews
most
recent
applications
(in
2024)
applied
to
resources.
Language: Английский
Optimized Iodine Recovery from Zinc Suboxide Derived from Steel Dust Using Alkaline Washing and Air Blowing-Out: A Sustainable Industrial Approach
Sustainability,
Journal Year:
2024,
Volume and Issue:
16(24), P. 10925 - 10925
Published: Dec. 13, 2024
The
present
paper
proposes
an
advanced
process
to
effectively
recover
and
fully
use
iodine
from
steel
dust-derived
zinc
suboxide,
with
considerations
of
effectiveness
in
the
industrial
viability.
It
includes,
for
example,
alkali
wash
dissolution
into
alkaline
solution
dust
uses
mechanical
vapor
recompression
(MVR)
concentrate
dissolved
by
preparing
air-blowing-out
process.
hydrogen
iodide
is
also
oxidized
under
acidic
conditions
addition
peroxide
form
crude
iodine,
estimated
at
about
20
tons
annually.
As
a
matter
fact,
using
this
process,
up
1.2
million
waste
can
be
treated
year,
turning
what
was
previously
considered
something
value.
thermodynamic
relationship
between
recovery
pH
value
further
discussed
study,
pointing
out
that
conditions,
predominantly
(I−)
iodate
(IO3−),
while
less
than
2.8,
it
its
molecular
I2.
These
insights
would
provide
theoretical
backbone
maximum
extraction
efficiency,
guiding
parameters
toward
optimum
judicious
resource.
Language: Английский